Organic Letters, volume 22, issue 8, pages 3056-3061

Gold(I)-Catalyzed [8+4] Cycloaddition of 1,4-All-Carbon Dipoles with Tropone

Publication typeJournal Article
Publication date2020-03-30
Journal: Organic Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.2
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Herein, we describe a gold(I)-catalyzed generation of nonclassical gold-containing 1,4-all-carbon dipoles from cycloisomerization/1,2-carbene transfer/ring opening cascade reactions of readily accessible allenyl ketones bearing a cyclopropyl moiety and its cyclization with tropone. This method features an unprecedented formal [8+4] high-order cycloaddition under mild conditions for delivering structurally complex 7,7,5-tricycles in generally moderate to high yields.

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GOST |
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GOST Copy
Zhang S. et al. Gold(I)-Catalyzed [8+4] Cycloaddition of 1,4-All-Carbon Dipoles with Tropone // Organic Letters. 2020. Vol. 22. No. 8. pp. 3056-3061.
GOST all authors (up to 50) Copy
Zhang S., Xie R., Tang A., Chen P., Zhao Z., Miao M., Ren H. Gold(I)-Catalyzed [8+4] Cycloaddition of 1,4-All-Carbon Dipoles with Tropone // Organic Letters. 2020. Vol. 22. No. 8. pp. 3056-3061.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.0c00810
UR - https://doi.org/10.1021/acs.orglett.0c00810
TI - Gold(I)-Catalyzed [8+4] Cycloaddition of 1,4-All-Carbon Dipoles with Tropone
T2 - Organic Letters
AU - Zhang, Shouzhi
AU - Xie, Ruyu
AU - Tang, Aijie
AU - Chen, Panpan
AU - Zhao, Zhiqiang
AU - Miao, Maozhong
AU - Ren, Hongjun
PY - 2020
DA - 2020/03/30 00:00:00
PB - American Chemical Society (ACS)
SP - 3056-3061
IS - 8
VL - 22
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex Copy
@article{2020_Zhang,
author = {Shouzhi Zhang and Ruyu Xie and Aijie Tang and Panpan Chen and Zhiqiang Zhao and Maozhong Miao and Hongjun Ren},
title = {Gold(I)-Catalyzed [8+4] Cycloaddition of 1,4-All-Carbon Dipoles with Tropone},
journal = {Organic Letters},
year = {2020},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.orglett.0c00810},
number = {8},
pages = {3056--3061},
doi = {10.1021/acs.orglett.0c00810}
}
MLA
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MLA Copy
Zhang, Shouzhi, et al. “Gold(I)-Catalyzed [8+4] Cycloaddition of 1,4-All-Carbon Dipoles with Tropone.” Organic Letters, vol. 22, no. 8, Mar. 2020, pp. 3056-3061. https://doi.org/10.1021/acs.orglett.0c00810.
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