Copper-Catalyzed Anti-Markovnikov Hydrosilylation of Terminal Alkynes
Publication type: Journal Article
Publication date: 2020-09-23
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
32966085
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A copper-catalyzed anti-Markovnikov hydrosilylation of alkynes with PhSiH3 was reported. This reaction represents a notable and efficient example on copper-catalyzed hydrosilylatioin of alkynes, which shows excellent recognition between the terminal and internal triple bonds. Various (hetero)aromatic and aliphatic substituted terminal alkynes underwent this reaction to afford the (E)-vinylsilanes in high yields and with excellent regioselectivity.
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Metrics
41
Total citations:
41
Citations from 2024:
21
(51.22%)
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MLA
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GOST
Copy
Wang Z. L. et al. Copper-Catalyzed Anti-Markovnikov Hydrosilylation of Terminal Alkynes // Organic Letters. 2020. Vol. 22. No. 19. pp. 7735-7742.
GOST all authors (up to 50)
Copy
Wang Z. L., Zhang F., Xu J. L., Shan C. C., Zhao M., Xu Y. Copper-Catalyzed Anti-Markovnikov Hydrosilylation of Terminal Alkynes // Organic Letters. 2020. Vol. 22. No. 19. pp. 7735-7742.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.0c02952
UR - https://doi.org/10.1021/acs.orglett.0c02952
TI - Copper-Catalyzed Anti-Markovnikov Hydrosilylation of Terminal Alkynes
T2 - Organic Letters
AU - Wang, Zi Lu
AU - Zhang, Fenglian
AU - Xu, Jian Lin
AU - Shan, Cui Cui
AU - Zhao, Meng
AU - Xu, Yunhe
PY - 2020
DA - 2020/09/23
PB - American Chemical Society (ACS)
SP - 7735-7742
IS - 19
VL - 22
PMID - 32966085
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Wang,
author = {Zi Lu Wang and Fenglian Zhang and Jian Lin Xu and Cui Cui Shan and Meng Zhao and Yunhe Xu},
title = {Copper-Catalyzed Anti-Markovnikov Hydrosilylation of Terminal Alkynes},
journal = {Organic Letters},
year = {2020},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.orglett.0c02952},
number = {19},
pages = {7735--7742},
doi = {10.1021/acs.orglett.0c02952}
}
Cite this
MLA
Copy
Wang, Zi Lu, et al. “Copper-Catalyzed Anti-Markovnikov Hydrosilylation of Terminal Alkynes.” Organic Letters, vol. 22, no. 19, Sep. 2020, pp. 7735-7742. https://doi.org/10.1021/acs.orglett.0c02952.