Single C–F Transformations of o-Hydrosilyl Benzotrifluorides with Trityl Compounds as All-in-One Reagents
Publication type: Journal Article
Publication date: 2020-11-12
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
33180503
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A facile method to prepare difluoromethylenes, including α,α-difluorobenzyl chlorides, by single C-F transformations of benzotrifluorides is disclosed. The C-F cleavage followed by chlorination proceeded smoothly using trityl chloride through the generation of trityl cation as an activator and chloride anion as a nucleophile. Diverse difluoromethylenes such as difluorobenzyl ethers were efficiently prepared by virtue of the good versatility of the resulting chloro and fluorosilyl groups.
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48
Total citations:
48
Citations from 2025:
7
(14.58%)
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GOST
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Idogawa R. et al. Single C–F Transformations of o-Hydrosilyl Benzotrifluorides with Trityl Compounds as All-in-One Reagents // Organic Letters. 2020. Vol. 22. No. 23. pp. 9292-9297.
GOST all authors (up to 50)
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Idogawa R., Kim Y., Shimomori K., Hosoya T., Yoshida S. Single C–F Transformations of o-Hydrosilyl Benzotrifluorides with Trityl Compounds as All-in-One Reagents // Organic Letters. 2020. Vol. 22. No. 23. pp. 9292-9297.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.0c03529
UR - https://doi.org/10.1021/acs.orglett.0c03529
TI - Single C–F Transformations of o-Hydrosilyl Benzotrifluorides with Trityl Compounds as All-in-One Reagents
T2 - Organic Letters
AU - Idogawa, Rika
AU - Kim, Youngchan
AU - Shimomori, Ken
AU - Hosoya, Takamitsu
AU - Yoshida, Suguru
PY - 2020
DA - 2020/11/12
PB - American Chemical Society (ACS)
SP - 9292-9297
IS - 23
VL - 22
PMID - 33180503
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Idogawa,
author = {Rika Idogawa and Youngchan Kim and Ken Shimomori and Takamitsu Hosoya and Suguru Yoshida},
title = {Single C–F Transformations of o-Hydrosilyl Benzotrifluorides with Trityl Compounds as All-in-One Reagents},
journal = {Organic Letters},
year = {2020},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.orglett.0c03529},
number = {23},
pages = {9292--9297},
doi = {10.1021/acs.orglett.0c03529}
}
Cite this
MLA
Copy
Idogawa, Rika, et al. “Single C–F Transformations of o-Hydrosilyl Benzotrifluorides with Trityl Compounds as All-in-One Reagents.” Organic Letters, vol. 22, no. 23, Nov. 2020, pp. 9292-9297. https://doi.org/10.1021/acs.orglett.0c03529.