Catalyst-Free Hydrodefluorination of Perfluoroarenes with NaBH4
Publication type: Journal Article
Publication date: 2021-02-15
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
33587637
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Presented is an economical means of removing fluorine from various highly fluorinated arenes using NaBH4. The procedure was adapted for different classes of perfluoroarenes. A novel isomer of an emerging class of organic dyes based on the carbazole phthalonitrile motif was succinctly synthesized in two steps from tetrafluorophthalonitrile, demonstrating the utility of the hydrodefluorination procedure. Initial exploration of the dye shows it to be photoactive and capable of facilitating contrathermodynamic styrenoid E/Z isomerization.
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Metrics
26
Total citations:
26
Citations from 2024:
8
(30.77%)
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MLA
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GOST
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Schoch T. D., Mondal M., Weaver J. D. Catalyst-Free Hydrodefluorination of Perfluoroarenes with NaBH4 // Organic Letters. 2021. Vol. 23. No. 5. pp. 1588-1593.
GOST all authors (up to 50)
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Schoch T. D., Mondal M., Weaver J. D. Catalyst-Free Hydrodefluorination of Perfluoroarenes with NaBH4 // Organic Letters. 2021. Vol. 23. No. 5. pp. 1588-1593.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.orglett.0c04305
UR - https://doi.org/10.1021/acs.orglett.0c04305
TI - Catalyst-Free Hydrodefluorination of Perfluoroarenes with NaBH4
T2 - Organic Letters
AU - Schoch, Timothy D
AU - Mondal, Mukulesh
AU - Weaver, Jimmie D
PY - 2021
DA - 2021/02/15
PB - American Chemical Society (ACS)
SP - 1588-1593
IS - 5
VL - 23
PMID - 33587637
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Schoch,
author = {Timothy D Schoch and Mukulesh Mondal and Jimmie D Weaver},
title = {Catalyst-Free Hydrodefluorination of Perfluoroarenes with NaBH4},
journal = {Organic Letters},
year = {2021},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.orglett.0c04305},
number = {5},
pages = {1588--1593},
doi = {10.1021/acs.orglett.0c04305}
}
Cite this
MLA
Copy
Schoch, Timothy D., et al. “Catalyst-Free Hydrodefluorination of Perfluoroarenes with NaBH4.” Organic Letters, vol. 23, no. 5, Feb. 2021, pp. 1588-1593. https://doi.org/10.1021/acs.orglett.0c04305.