Iron-Catalyzed Regio- and Stereoselective Hydrosilylation of 1,3-Enynes To Access 1,3-Dienylsilanes
Publication type: Journal Article
Publication date: 2021-03-10
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
33689387
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A regio- and stereoselective hydrosilylation of 1,3-enynes with primary and secondary silanes to access 1,3-dienylsilanes is accomplished by employing an iron precatalyst bearing iminopyridine-oxazoline (IPO) ligand. The hydrosilylation proceeds via syn-addition of a Si-H bond to the alkyne group of 1,3-enynes, incorporating the silyl group at the site proximal to the alkene. The reaction features mild conditions, broad substrate scope, and good functional group tolerance. The synthetic utility was demonstrated by gram-scale reactions and further transformations.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
|
|
|
Organic Letters
3 publications, 9.09%
|
|
|
Journal of the American Chemical Society
2 publications, 6.06%
|
|
|
Chemistry - A European Journal
2 publications, 6.06%
|
|
|
Catalysis Science and Technology
2 publications, 6.06%
|
|
|
ACS Catalysis
2 publications, 6.06%
|
|
|
Organic Chemistry Frontiers
2 publications, 6.06%
|
|
|
Chemical Communications
2 publications, 6.06%
|
|
|
Chemistry - An Asian Journal
1 publication, 3.03%
|
|
|
Organometallics
1 publication, 3.03%
|
|
|
Organic and Biomolecular Chemistry
1 publication, 3.03%
|
|
|
Science China Chemistry
1 publication, 3.03%
|
|
|
Asian Journal of Organic Chemistry
1 publication, 3.03%
|
|
|
Journal of Organic Chemistry
1 publication, 3.03%
|
|
|
Chem
1 publication, 3.03%
|
|
|
Nature Communications
1 publication, 3.03%
|
|
|
Topics in Organometallic Chemistry
1 publication, 3.03%
|
|
|
iScience
1 publication, 3.03%
|
|
|
Applied Organometallic Chemistry
1 publication, 3.03%
|
|
|
Angewandte Chemie
1 publication, 3.03%
|
|
|
Angewandte Chemie - International Edition
1 publication, 3.03%
|
|
|
ChemCatChem
1 publication, 3.03%
|
|
|
Russian Chemical Reviews
1 publication, 3.03%
|
|
|
Molecules
1 publication, 3.03%
|
|
|
Chemical Record
1 publication, 3.03%
|
|
|
1
2
3
|
Publishers
|
1
2
3
4
5
6
7
8
9
|
|
|
Wiley
9 publications, 27.27%
|
|
|
American Chemical Society (ACS)
9 publications, 27.27%
|
|
|
Royal Society of Chemistry (RSC)
7 publications, 21.21%
|
|
|
Springer Nature
3 publications, 9.09%
|
|
|
Elsevier
2 publications, 6.06%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 3.03%
|
|
|
MDPI
1 publication, 3.03%
|
|
|
1
2
3
4
5
6
7
8
9
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
33
Total citations:
33
Citations from 2024:
18
(54.54%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Guo Z. et al. Iron-Catalyzed Regio- and Stereoselective Hydrosilylation of 1,3-Enynes To Access 1,3-Dienylsilanes // Organic Letters. 2021. Vol. 23. No. 6. pp. 2375-2379.
GOST all authors (up to 50)
Copy
Guo Z., Wen H., Liu G., Huang Z. Iron-Catalyzed Regio- and Stereoselective Hydrosilylation of 1,3-Enynes To Access 1,3-Dienylsilanes // Organic Letters. 2021. Vol. 23. No. 6. pp. 2375-2379.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.1c00670
UR - https://doi.org/10.1021/acs.orglett.1c00670
TI - Iron-Catalyzed Regio- and Stereoselective Hydrosilylation of 1,3-Enynes To Access 1,3-Dienylsilanes
T2 - Organic Letters
AU - Guo, Zhihao
AU - Wen, Huanan
AU - Liu, Guixia
AU - Huang, Zheng
PY - 2021
DA - 2021/03/10
PB - American Chemical Society (ACS)
SP - 2375-2379
IS - 6
VL - 23
PMID - 33689387
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Guo,
author = {Zhihao Guo and Huanan Wen and Guixia Liu and Zheng Huang},
title = {Iron-Catalyzed Regio- and Stereoselective Hydrosilylation of 1,3-Enynes To Access 1,3-Dienylsilanes},
journal = {Organic Letters},
year = {2021},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.orglett.1c00670},
number = {6},
pages = {2375--2379},
doi = {10.1021/acs.orglett.1c00670}
}
Cite this
MLA
Copy
Guo, Zhihao, et al. “Iron-Catalyzed Regio- and Stereoselective Hydrosilylation of 1,3-Enynes To Access 1,3-Dienylsilanes.” Organic Letters, vol. 23, no. 6, Mar. 2021, pp. 2375-2379. https://doi.org/10.1021/acs.orglett.1c00670.