volume 23 issue 11 pages 4173-4178

Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands

Publication typeJournal Article
Publication date2021-05-17
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
1,4,8-Triazaocta-1,3,5,7-tetraenes, generated in situ by Rh2(Piv)4-catalyzed denitrogenative coupling of pyrazoles with 1-sulfonyl-1,2,3-triazoles, smoothly form 2,6,8-triazabicyclo[3.2.1]octa-3,6-dienes via intramolecular aza-Diels-Alder cycloaddition. This domino reaction, combined with the subsequent thermal or acid-catalyzed rearrangement of the cycloadducts, provides direct and flexible access to N-sulfonylated (Z)-2-(2-aminovinyl)imidazoles.
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Strelnikova J. O. et al. Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands // Organic Letters. 2021. Vol. 23. No. 11. pp. 4173-4178.
GOST all authors (up to 50) Copy
Strelnikova J. O., Koronatov A., Koronatov A. N., Rostovskii N. V., Khlebnikov A. F., Khoroshilova O. V., Kryukova M. A., Novikov M. S. Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands // Organic Letters. 2021. Vol. 23. No. 11. pp. 4173-4178.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.1c01092
UR - https://pubs.acs.org/doi/10.1021/acs.orglett.1c01092
TI - Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands
T2 - Organic Letters
AU - Strelnikova, Julia O
AU - Koronatov, Aleksandr
AU - Koronatov, Alexander N
AU - Rostovskii, Nikolai V
AU - Khlebnikov, Alexander F
AU - Khoroshilova, Olesya V
AU - Kryukova, Mariya A
AU - Novikov, Mikhail S.
PY - 2021
DA - 2021/05/17
PB - American Chemical Society (ACS)
SP - 4173-4178
IS - 11
VL - 23
PMID - 33999636
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Strelnikova,
author = {Julia O Strelnikova and Aleksandr Koronatov and Alexander N Koronatov and Nikolai V Rostovskii and Alexander F Khlebnikov and Olesya V Khoroshilova and Mariya A Kryukova and Mikhail S. Novikov},
title = {Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands},
journal = {Organic Letters},
year = {2021},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://pubs.acs.org/doi/10.1021/acs.orglett.1c01092},
number = {11},
pages = {4173--4178},
doi = {10.1021/acs.orglett.1c01092}
}
MLA
Cite this
MLA Copy
Strelnikova, Julia O., et al. “Rhodium-Catalyzed Denitrogenative Diazole–Triazole Coupling toward Aza-Bridged Structures and Imidazole-Based Chelating Ligands.” Organic Letters, vol. 23, no. 11, May. 2021, pp. 4173-4178. https://pubs.acs.org/doi/10.1021/acs.orglett.1c01092.