volume 23 issue 19 pages 7661-7665

Thiophene-Fused BODIPY Dimers and Tetramers from Oxidative Aromatic Couplings as Near-Infrared Dyes

Publication typeJournal Article
Publication date2021-09-21
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
We describe a straightforward, postmodification synthesis for a family of thiophene-fused BODIPY dimers and tetramers through transforming flexible sulfur bridges into coplanar thiophene fusions. FeCl3 was used as a bifunctional oxidant for both intramolecular and intermolecular oxidative aromatic coupling reactions. Oxidative fusion and dimerization gave strong red-shift absorptions from 509 nm for a BODIPY monomer to 830 nm for a tetramer.
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GOST |
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GOST Copy
Gong Q. et al. Thiophene-Fused BODIPY Dimers and Tetramers from Oxidative Aromatic Couplings as Near-Infrared Dyes // Organic Letters. 2021. Vol. 23. No. 19. pp. 7661-7665.
GOST all authors (up to 50) Copy
Gong Q., Wu Q., Guo X., Li H., Li W., Yu C., Hao E., Jiao L. Thiophene-Fused BODIPY Dimers and Tetramers from Oxidative Aromatic Couplings as Near-Infrared Dyes // Organic Letters. 2021. Vol. 23. No. 19. pp. 7661-7665.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.1c02926
UR - https://doi.org/10.1021/acs.orglett.1c02926
TI - Thiophene-Fused BODIPY Dimers and Tetramers from Oxidative Aromatic Couplings as Near-Infrared Dyes
T2 - Organic Letters
AU - Gong, Qingbao
AU - Wu, Qinghua
AU - Guo, Xing
AU - Li, Heng
AU - Li, Wanwan
AU - Yu, Changjiang
AU - Hao, Erhong
AU - Jiao, Lijuan
PY - 2021
DA - 2021/09/21
PB - American Chemical Society (ACS)
SP - 7661-7665
IS - 19
VL - 23
PMID - 34546062
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Gong,
author = {Qingbao Gong and Qinghua Wu and Xing Guo and Heng Li and Wanwan Li and Changjiang Yu and Erhong Hao and Lijuan Jiao},
title = {Thiophene-Fused BODIPY Dimers and Tetramers from Oxidative Aromatic Couplings as Near-Infrared Dyes},
journal = {Organic Letters},
year = {2021},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.orglett.1c02926},
number = {19},
pages = {7661--7665},
doi = {10.1021/acs.orglett.1c02926}
}
MLA
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MLA Copy
Gong, Qingbao, et al. “Thiophene-Fused BODIPY Dimers and Tetramers from Oxidative Aromatic Couplings as Near-Infrared Dyes.” Organic Letters, vol. 23, no. 19, Sep. 2021, pp. 7661-7665. https://doi.org/10.1021/acs.orglett.1c02926.