, volume 23 , issue 22 , pages 8968-8972

Iron-Catalyzed Photoinduced Remote C(sp³)–H Amination of Free Alcohols

Ni Xiong ¹

Yang Li ¹

Rong Zeng ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

School of Chemistry, MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi’an Key Laboratory of Sustainable Energy Materials Chemistry, Xi’an Jiaotong University, Xi’an 710049, P. R. China |

Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen 518055, Guangdong, P. R. China |

Publication type: Journal Article

Publication date: 2021-10-29

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5.0

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.1c03488

Copy DOI

PubMed ID: 34714097

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Abstract

We report a general photocatalytic protocol for the remote C(sp3)-H bond amination of free aliphatic alcohols. The electron transfer between the abundant and inexpensive catalyst FeCl3 and simple alkanols under blue LED irradiation enables the alkoxy radical formation under mild redox-neutral conditions, with no need for additional oxidant and prefunctionalization. The subsequent selective 1,5-hydrogen atom transfer (HAT) and amination provide a simple and efficient way to access molecular complexity from readily available and bulk alcohols.

Found

Top-30

Journals

	1 2 3 4 5 6 7 8 9
Organic Letters	Organic Letters, 9, 14.29% Organic Letters 9 publications, 14.29%
Organic Chemistry Frontiers	Organic Chemistry Frontiers, 5, 7.94% Organic Chemistry Frontiers 5 publications, 7.94%
European Journal of Organic Chemistry	European Journal of Organic Chemistry, 4, 6.35% European Journal of Organic Chemistry 4 publications, 6.35%
ACS Catalysis	ACS Catalysis, 3, 4.76% ACS Catalysis 3 publications, 4.76%
Chemical Communications	Chemical Communications, 3, 4.76% Chemical Communications 3 publications, 4.76%
Advanced Synthesis and Catalysis	Advanced Synthesis and Catalysis, 3, 4.76% Advanced Synthesis and Catalysis 3 publications, 4.76%
ChemSusChem	ChemSusChem, 3, 4.76% ChemSusChem 3 publications, 4.76%
ChemCatChem	ChemCatChem, 3, 4.76% ChemCatChem 3 publications, 4.76%
Chemical Science	Chemical Science, 3, 4.76% Chemical Science 3 publications, 4.76%
Synthesis	Synthesis, 2, 3.17% Synthesis 2 publications, 3.17%
Journal of Organic Chemistry	Journal of Organic Chemistry, 2, 3.17% Journal of Organic Chemistry 2 publications, 3.17%
Green Chemistry	Green Chemistry, 2, 3.17% Green Chemistry 2 publications, 3.17%
Organic and Biomolecular Chemistry	Organic and Biomolecular Chemistry, 2, 3.17% Organic and Biomolecular Chemistry 2 publications, 3.17%
Chemistry - A European Journal	Chemistry - A European Journal, 2, 3.17% Chemistry - A European Journal 2 publications, 3.17%
Chinese Journal of Organic Chemistry	Chinese Journal of Organic Chemistry, 1, 1.59% Chinese Journal of Organic Chemistry 1 publication, 1.59%
Green Synthesis and Catalysis	Green Synthesis and Catalysis, 1, 1.59% Green Synthesis and Catalysis 1 publication, 1.59%
Journal of the American Chemical Society	Journal of the American Chemical Society, 1, 1.59% Journal of the American Chemical Society 1 publication, 1.59%
Organic Process Research and Development	Organic Process Research and Development, 1, 1.59% Organic Process Research and Development 1 publication, 1.59%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 1, 1.59% Coordination Chemistry Reviews 1 publication, 1.59%
Chemistry - An Asian Journal	Chemistry - An Asian Journal, 1, 1.59% Chemistry - An Asian Journal 1 publication, 1.59%
Chinese Chemical Letters	Chinese Chemical Letters, 1, 1.59% Chinese Chemical Letters 1 publication, 1.59%
ChemistrySelect	ChemistrySelect, 1, 1.59% ChemistrySelect 1 publication, 1.59%
Nature Communications	Nature Communications, 1, 1.59% Nature Communications 1 publication, 1.59%
Chemical Reviews	Chemical Reviews, 1, 1.59% Chemical Reviews 1 publication, 1.59%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 1.59% Russian Chemical Reviews 1 publication, 1.59%
Chem Catalysis	Chem Catalysis, 1, 1.59% Chem Catalysis 1 publication, 1.59%
Chemical Society Reviews	Chemical Society Reviews, 1, 1.59% Chemical Society Reviews 1 publication, 1.59%
Asian Journal of Organic Chemistry	Asian Journal of Organic Chemistry, 1, 1.59% Asian Journal of Organic Chemistry 1 publication, 1.59%
ACS Central Science	ACS Central Science, 1, 1.59% ACS Central Science 1 publication, 1.59%
	1 2 3 4 5 6 7 8 9

Publishers

	2 4 6 8 10 12 14 16 18
American Chemical Society (ACS)	American Chemical Society (ACS), 18, 28.57% American Chemical Society (ACS) 18 publications, 28.57%
Wiley	Wiley, 18, 28.57% Wiley 18 publications, 28.57%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 16, 25.4% Royal Society of Chemistry (RSC) 16 publications, 25.4%
Elsevier	Elsevier, 5, 7.94% Elsevier 5 publications, 7.94%
Georg Thieme Verlag KG	Georg Thieme Verlag KG, 2, 3.17% Georg Thieme Verlag KG 2 publications, 3.17%
Springer Nature	Springer Nature, 2, 3.17% Springer Nature 2 publications, 3.17%
Shanghai Institute of Organic Chemistry	Shanghai Institute of Organic Chemistry, 1, 1.59% Shanghai Institute of Organic Chemistry 1 publication, 1.59%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.59% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.59%
	2 4 6 8 10 12 14 16 18

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Xiong N. et al. Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols // Organic Letters. 2021. Vol. 23. No. 22. pp. 8968-8972.

GOST all authors (up to 50) Copy

Xiong N., Li Y., Zeng R. Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols // Organic Letters. 2021. Vol. 23. No. 22. pp. 8968-8972.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/acs.orglett.1c03488

UR - https://doi.org/10.1021/acs.orglett.1c03488

TI - Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols

T2 - Organic Letters

AU - Xiong, Ni

AU - Li, Yang

AU - Zeng, Rong

PY - 2021

DA - 2021/10/29

PB - American Chemical Society (ACS)

SP - 8968-8972

IS - 22

VL - 23

PMID - 34714097

SN - 1523-7060

SN - 1523-7052

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2021_Xiong,

author = {Ni Xiong and Yang Li and Rong Zeng},

title = {Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols},

journal = {Organic Letters},

year = {2021},

volume = {23},

publisher = {American Chemical Society (ACS)},

month = {oct},

url = {https://doi.org/10.1021/acs.orglett.1c03488},

number = {22},

pages = {8968--8972},

doi = {10.1021/acs.orglett.1c03488}

}

MLA

Cite this

MLA Copy

Xiong, Ni, et al. “Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols.” Organic Letters, vol. 23, no. 22, Oct. 2021, pp. 8968-8972. https://doi.org/10.1021/acs.orglett.1c03488.

Publisher

American Chemical Society (ACS)

Journal

Organic Letters

scimago Q1

wos Q1

SJR

1.235

CiteScore

8.7

Impact factor

5.0

ISSN

15237060 (Print)

15237052 (Electronic)