Organic Letters, volume 23, issue 22, pages 8968-8972
Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols
Publication type: Journal Article
Publication date: 2021-10-29
Journal:
Organic Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.2
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
We report a general photocatalytic protocol for the remote C(sp3)-H bond amination of free aliphatic alcohols. The electron transfer between the abundant and inexpensive catalyst FeCl3 and simple alkanols under blue LED irradiation enables the alkoxy radical formation under mild redox-neutral conditions, with no need for additional oxidant and prefunctionalization. The subsequent selective 1,5-hydrogen atom transfer (HAT) and amination provide a simple and efficient way to access molecular complexity from readily available and bulk alcohols.
Top-30
Citations by journals
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8 publications, 16.33%
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3 publications, 6.12%
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European Journal of Organic Chemistry
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3 publications, 6.12%
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2 publications, 4.08%
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2 publications, 4.08%
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2 publications, 4.08%
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Green Chemistry
2 publications, 4.08%
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2 publications, 4.08%
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Chinese Journal of Organic Chemistry
1 publication, 2.04%
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Green Synthesis and Catalysis
1 publication, 2.04%
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Journal of the American Chemical Society
1 publication, 2.04%
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1 publication, 2.04%
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1 publication, 2.04%
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Coordination Chemistry Reviews
1 publication, 2.04%
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Chemistry - An Asian Journal
1 publication, 2.04%
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Chinese Chemical Letters
1 publication, 2.04%
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ChemistrySelect
1 publication, 2.04%
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Nature Communications
1 publication, 2.04%
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Chemical Reviews
1 publication, 2.04%
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Russian Chemical Reviews
1 publication, 2.04%
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Citations by publishers
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16
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American Chemical Society (ACS)
16 publications, 32.65%
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Wiley
14 publications, 28.57%
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Royal Society of Chemistry (RSC)
10 publications, 20.41%
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Elsevier
4 publications, 8.16%
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Thieme
2 publications, 4.08%
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Shanghai Institute of Organic Chemistry
1 publication, 2.04%
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Springer Nature
1 publication, 2.04%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.04%
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16
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Xiong N. et al. Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols // Organic Letters. 2021. Vol. 23. No. 22. pp. 8968-8972.
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Xiong N., Li Y., Zeng R. Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols // Organic Letters. 2021. Vol. 23. No. 22. pp. 8968-8972.
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TY - JOUR
DO - 10.1021/acs.orglett.1c03488
UR - https://doi.org/10.1021/acs.orglett.1c03488
TI - Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols
T2 - Organic Letters
AU - Xiong, Ni
AU - Li, Yang
AU - Zeng, Rong
PY - 2021
DA - 2021/10/29 00:00:00
PB - American Chemical Society (ACS)
SP - 8968-8972
IS - 22
VL - 23
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex
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@article{2021_Xiong,
author = {Ni Xiong and Yang Li and Rong Zeng},
title = {Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols},
journal = {Organic Letters},
year = {2021},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.orglett.1c03488},
number = {22},
pages = {8968--8972},
doi = {10.1021/acs.orglett.1c03488}
}
Cite this
MLA
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Xiong, Ni, et al. “Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols.” Organic Letters, vol. 23, no. 22, Oct. 2021, pp. 8968-8972. https://doi.org/10.1021/acs.orglett.1c03488.