volume 23 issue 23 pages 9227-9231

Synthetic Studies toward the Berkeleyacetal Core Architecture

Publication typeJournal Article
Publication date2021-11-15
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Berkeleyacetals are structurally complex natural products that have shown potent anti-inflammatory activity. The presence of a highly dense oxygen functionality and a polycyclic ring system presents significant synthetic challenges. Herein, we report an efficient strategy for the construction of the tetracyclic core system of berkeleyacetal. Our synthetic strategy features two cycloadditions ([4+2] and [5+2]) to forge the tetracyclic core and Achmatowicz rearrangement for the preparation of the cyclization substrates containing B and E rings.
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GOST |
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GOST Copy
Márquez Cadena M. A., Wei Y., Tong R. Synthetic Studies toward the Berkeleyacetal Core Architecture // Organic Letters. 2021. Vol. 23. No. 23. pp. 9227-9231.
GOST all authors (up to 50) Copy
Márquez Cadena M. A., Wei Y., Tong R. Synthetic Studies toward the Berkeleyacetal Core Architecture // Organic Letters. 2021. Vol. 23. No. 23. pp. 9227-9231.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.1c03559
UR - https://doi.org/10.1021/acs.orglett.1c03559
TI - Synthetic Studies toward the Berkeleyacetal Core Architecture
T2 - Organic Letters
AU - Márquez Cadena, Miguel Adrián
AU - Wei, Yi-ping
AU - Tong, Rong-Biao
PY - 2021
DA - 2021/11/15
PB - American Chemical Society (ACS)
SP - 9227-9231
IS - 23
VL - 23
PMID - 34780201
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Márquez Cadena,
author = {Miguel Adrián Márquez Cadena and Yi-ping Wei and Rong-Biao Tong},
title = {Synthetic Studies toward the Berkeleyacetal Core Architecture},
journal = {Organic Letters},
year = {2021},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acs.orglett.1c03559},
number = {23},
pages = {9227--9231},
doi = {10.1021/acs.orglett.1c03559}
}
MLA
Cite this
MLA Copy
Márquez Cadena, Miguel Adrián, et al. “Synthetic Studies toward the Berkeleyacetal Core Architecture.” Organic Letters, vol. 23, no. 23, Nov. 2021, pp. 9227-9231. https://doi.org/10.1021/acs.orglett.1c03559.