Cobalt-Catalyzed Fluoroallyllation of Carbonyls via C–C Activation of gem-Difluorocyclopropanes
Publication type: Journal Article
Publication date: 2022-07-14
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
35833731
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A new Co-catalyzed sequential C-C and C-F activation of gem-difluorinated cyclopropanes (gem-FCPs) to form nucleophilic fluoroallylcobalt, followed by addition to aldehydes, is reported. The protocol features the regioselective cleavage of dual chemical bonds of readily available gem-FCPs to prepare easily separable linear (Z)- and (E)-fluorinated homoallylic alcohols with a broad scope. This discovery established a new strategy for the efficient transformation of gem-FCPs as well as the synthesis of challenging fluorinated homoallylic alcohols.
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43
Total citations:
43
Citations from 2025:
10
(23.25%)
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MLA
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GOST
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Ai Y. et al. Cobalt-Catalyzed Fluoroallyllation of Carbonyls via C–C Activation of gem-Difluorocyclopropanes // Organic Letters. 2022. Vol. 24. No. 28. pp. 5051-5055.
GOST all authors (up to 50)
Copy
Ai Y., Yang H., Duan C., Li X., Yu S. Cobalt-Catalyzed Fluoroallyllation of Carbonyls via C–C Activation of gem-Difluorocyclopropanes // Organic Letters. 2022. Vol. 24. No. 28. pp. 5051-5055.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.2c01821
UR - https://doi.org/10.1021/acs.orglett.2c01821
TI - Cobalt-Catalyzed Fluoroallyllation of Carbonyls via C–C Activation of gem-Difluorocyclopropanes
T2 - Organic Letters
AU - Ai, Yinan
AU - Yang, Hanlin
AU - Duan, Chunying
AU - Li, Xingwei
AU - Yu, Songjie
PY - 2022
DA - 2022/07/14
PB - American Chemical Society (ACS)
SP - 5051-5055
IS - 28
VL - 24
PMID - 35833731
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Ai,
author = {Yinan Ai and Hanlin Yang and Chunying Duan and Xingwei Li and Songjie Yu},
title = {Cobalt-Catalyzed Fluoroallyllation of Carbonyls via C–C Activation of gem-Difluorocyclopropanes},
journal = {Organic Letters},
year = {2022},
volume = {24},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.orglett.2c01821},
number = {28},
pages = {5051--5055},
doi = {10.1021/acs.orglett.2c01821}
}
Cite this
MLA
Copy
Ai, Yinan, et al. “Cobalt-Catalyzed Fluoroallyllation of Carbonyls via C–C Activation of gem-Difluorocyclopropanes.” Organic Letters, vol. 24, no. 28, Jul. 2022, pp. 5051-5055. https://doi.org/10.1021/acs.orglett.2c01821.