Organic Letters, volume 24, issue 31, pages 5726-5730

Visible-Light-Induced Decarboxylative Alkylation/Ring Opening and Esterification of Vinylcyclopropanes

Publication typeJournal Article
Publication date2022-08-03
Journal: Organic Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.2
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A visible-light-induced four-component reaction of vinylcyclopropanes, N-(acyloxy)phthalimide esters, N,N-dimethylformamide (DMF), and H2O through an oxidative ring opening of cyclopropane is presented. This procedure provides a new and effective way to construct formate esters. DMF is employed as both a solvent and the source of CHO. This difunctionalization of vinylcyclopropanes shows good functional group tolerance under room temperature. A radical pathway is involved, and carbonyl oxygen of ester originated from water in this transformation.

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GOST |
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GOST Copy
Chen P. et al. Visible-Light-Induced Decarboxylative Alkylation/Ring Opening and Esterification of Vinylcyclopropanes // Organic Letters. 2022. Vol. 24. No. 31. pp. 5726-5730.
GOST all authors (up to 50) Copy
Chen P., Huang P. F., Xiong B., Huang H., Tang K., Liu Yu. Visible-Light-Induced Decarboxylative Alkylation/Ring Opening and Esterification of Vinylcyclopropanes // Organic Letters. 2022. Vol. 24. No. 31. pp. 5726-5730.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acs.orglett.2c02151
UR - https://doi.org/10.1021/acs.orglett.2c02151
TI - Visible-Light-Induced Decarboxylative Alkylation/Ring Opening and Esterification of Vinylcyclopropanes
T2 - Organic Letters
AU - Chen, Pu
AU - Huang, Peng Fei
AU - Xiong, Biquan
AU - Huang, Huawen
AU - Tang, Kewen
AU - Liu, Yu
PY - 2022
DA - 2022/08/03 00:00:00
PB - American Chemical Society (ACS)
SP - 5726-5730
IS - 31
VL - 24
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex Copy
@article{2022_Chen,
author = {Pu Chen and Peng Fei Huang and Biquan Xiong and Huawen Huang and Kewen Tang and Yu Liu},
title = {Visible-Light-Induced Decarboxylative Alkylation/Ring Opening and Esterification of Vinylcyclopropanes},
journal = {Organic Letters},
year = {2022},
volume = {24},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.orglett.2c02151},
number = {31},
pages = {5726--5730},
doi = {10.1021/acs.orglett.2c02151}
}
MLA
Cite this
MLA Copy
Chen, Pu, et al. “Visible-Light-Induced Decarboxylative Alkylation/Ring Opening and Esterification of Vinylcyclopropanes.” Organic Letters, vol. 24, no. 31, Aug. 2022, pp. 5726-5730. https://doi.org/10.1021/acs.orglett.2c02151.
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