Ligandless Regioselective Hydrosilylation of Allenes Catalyzed by Gold Nanoparticles.
Publication type: Journal Article
Publication date: 2015-09-02
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
26331196
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The first example of Au-catalyzed hydrosilylation of allenes is presented using recyclable gold nanoparticles as catalyst, without the requirement of any external ligands or additives. The hydrosilane addition takes place on the more substituted double bond of terminal allenes in a highly regioselective manner. The observed regioselectivity/reactivity modes are attributed to steric and electronic factors.
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77
Total citations:
77
Citations from 2024:
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(6.5%)
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GOST
Copy
Kidonakis M., Stratakis M. Ligandless Regioselective Hydrosilylation of Allenes Catalyzed by Gold Nanoparticles. // Organic Letters. 2015. Vol. 17. No. 18. pp. 4538-4541.
GOST all authors (up to 50)
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Kidonakis M., Stratakis M. Ligandless Regioselective Hydrosilylation of Allenes Catalyzed by Gold Nanoparticles. // Organic Letters. 2015. Vol. 17. No. 18. pp. 4538-4541.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.5b02236
UR - https://doi.org/10.1021/acs.orglett.5b02236
TI - Ligandless Regioselective Hydrosilylation of Allenes Catalyzed by Gold Nanoparticles.
T2 - Organic Letters
AU - Kidonakis, Marios
AU - Stratakis, Manolis
PY - 2015
DA - 2015/09/02
PB - American Chemical Society (ACS)
SP - 4538-4541
IS - 18
VL - 17
PMID - 26331196
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Kidonakis,
author = {Marios Kidonakis and Manolis Stratakis},
title = {Ligandless Regioselective Hydrosilylation of Allenes Catalyzed by Gold Nanoparticles.},
journal = {Organic Letters},
year = {2015},
volume = {17},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.orglett.5b02236},
number = {18},
pages = {4538--4541},
doi = {10.1021/acs.orglett.5b02236}
}
Cite this
MLA
Copy
Kidonakis, Marios, and Manolis Stratakis. “Ligandless Regioselective Hydrosilylation of Allenes Catalyzed by Gold Nanoparticles..” Organic Letters, vol. 17, no. 18, Sep. 2015, pp. 4538-4541. https://doi.org/10.1021/acs.orglett.5b02236.