Highly Regioselective α-Chlorination of the BODIPY Chromophore with Copper(II) Chloride
Xin Zhou
1
,
Changjiang Yu
1
,
Zeya Feng
1
,
Yang Yu
1
,
Jun Wang
1
,
Erhong Hao
1
,
Yun Wei
1
,
Xiaolong Mu
1
,
Publication type: Journal Article
Publication date: 2015-09-04
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
26340068
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A general and efficient method for α-chlorination of 4,4'-difluoro-4-bora-3a,4a-diaza-s-indacenes (BODIPYs) has been developed using CuCl2 as chlorination reagent. The reaction is characterized by complete 3/5-positions of BODIPY regioselectivity. This unusual highly regioselective α-halogenation of BODIPY is in sharp contrast to previously reported halogenation methods which preferred to occur first at the 2,6-positions of BODIPY. This approach provides a straightforward, facile, and economical route to 3- and/or 5-chloroBODIPYs with various meso-groups (H, alkyl, and aryl) and their derivatives.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
14
|
|
|
Journal of Organic Chemistry
13 publications, 13.13%
|
|
|
Organic Letters
10 publications, 10.1%
|
|
|
Chemical Communications
8 publications, 8.08%
|
|
|
Chemistry - A European Journal
5 publications, 5.05%
|
|
|
Organic and Biomolecular Chemistry
5 publications, 5.05%
|
|
|
Tetrahedron
4 publications, 4.04%
|
|
|
European Journal of Organic Chemistry
4 publications, 4.04%
|
|
|
Dyes and Pigments
3 publications, 3.03%
|
|
|
Molecules
2 publications, 2.02%
|
|
|
Advanced Synthesis and Catalysis
2 publications, 2.02%
|
|
|
Angewandte Chemie - International Edition
2 publications, 2.02%
|
|
|
Angewandte Chemie
2 publications, 2.02%
|
|
|
Journal of the American Chemical Society
2 publications, 2.02%
|
|
|
ACS Omega
2 publications, 2.02%
|
|
|
Journal of Physical Chemistry Letters
2 publications, 2.02%
|
|
|
Chemical Science
2 publications, 2.02%
|
|
|
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
2 publications, 2.02%
|
|
|
Communications Chemistry
1 publication, 1.01%
|
|
|
Journal of Porphyrins and Phthalocyanines
1 publication, 1.01%
|
|
|
Chinese Journal of Organic Chemistry
1 publication, 1.01%
|
|
|
Crystals
1 publication, 1.01%
|
|
|
Mendeleev Communications
1 publication, 1.01%
|
|
|
Materials Chemistry and Physics
1 publication, 1.01%
|
|
|
Chinese Chemical Letters
1 publication, 1.01%
|
|
|
Coordination Chemistry Reviews
1 publication, 1.01%
|
|
|
Journal of Photochemistry and Photobiology A: Chemistry
1 publication, 1.01%
|
|
|
ChemPhysChem
1 publication, 1.01%
|
|
|
ChemPhotoChem
1 publication, 1.01%
|
|
|
Chemistry - An Asian Journal
1 publication, 1.01%
|
|
|
Organometallics
1 publication, 1.01%
|
|
|
2
4
6
8
10
12
14
|
Publishers
|
5
10
15
20
25
30
35
|
|
|
American Chemical Society (ACS)
32 publications, 32.32%
|
|
|
Wiley
21 publications, 21.21%
|
|
|
Royal Society of Chemistry (RSC)
19 publications, 19.19%
|
|
|
Elsevier
14 publications, 14.14%
|
|
|
MDPI
4 publications, 4.04%
|
|
|
Springer Nature
2 publications, 2.02%
|
|
|
Taylor & Francis
2 publications, 2.02%
|
|
|
World Scientific
1 publication, 1.01%
|
|
|
Shanghai Institute of Organic Chemistry
1 publication, 1.01%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 1.01%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.01%
|
|
|
5
10
15
20
25
30
35
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
99
Total citations:
99
Citations from 2024:
19
(19.19%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Zhou X. et al. Highly Regioselective α-Chlorination of the BODIPY Chromophore with Copper(II) Chloride // Organic Letters. 2015. Vol. 17. No. 18. pp. 4632-4635.
GOST all authors (up to 50)
Copy
Zhou X., Yu C., Feng Z., Yu Y., Wang J., Hao E., Wei Y., Mu X., Jiao L. Highly Regioselective α-Chlorination of the BODIPY Chromophore with Copper(II) Chloride // Organic Letters. 2015. Vol. 17. No. 18. pp. 4632-4635.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.5b02383
UR - https://doi.org/10.1021/acs.orglett.5b02383
TI - Highly Regioselective α-Chlorination of the BODIPY Chromophore with Copper(II) Chloride
T2 - Organic Letters
AU - Zhou, Xin
AU - Yu, Changjiang
AU - Feng, Zeya
AU - Yu, Yang
AU - Wang, Jun
AU - Hao, Erhong
AU - Wei, Yun
AU - Mu, Xiaolong
AU - Jiao, Lijuan
PY - 2015
DA - 2015/09/04
PB - American Chemical Society (ACS)
SP - 4632-4635
IS - 18
VL - 17
PMID - 26340068
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Zhou,
author = {Xin Zhou and Changjiang Yu and Zeya Feng and Yang Yu and Jun Wang and Erhong Hao and Yun Wei and Xiaolong Mu and Lijuan Jiao},
title = {Highly Regioselective α-Chlorination of the BODIPY Chromophore with Copper(II) Chloride},
journal = {Organic Letters},
year = {2015},
volume = {17},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.orglett.5b02383},
number = {18},
pages = {4632--4635},
doi = {10.1021/acs.orglett.5b02383}
}
Cite this
MLA
Copy
Zhou, Xin, et al. “Highly Regioselective α-Chlorination of the BODIPY Chromophore with Copper(II) Chloride.” Organic Letters, vol. 17, no. 18, Sep. 2015, pp. 4632-4635. https://doi.org/10.1021/acs.orglett.5b02383.