Organic Letters, volume 17, issue 21, pages 5384-5387
Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives
Publication type: Journal Article
Publication date: 2015-10-26
Journal:
Organic Letters
Q1
Q1
SJR: 1.245
CiteScore: 9.3
Impact factor: 4.9
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
An efficient and general method for the synthesis of difluoroalkylated phenanthridine derivatives through palladium-catalyzed reaction of difluoroalkyl bromides with isocyanides is described. The reaction can also be extended to perfluoroalkyl iodides. Mechanistic studies reveal that a difluoroalkyl radical via a single-electron-transfer pathway is involved in the reaction.
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GOST
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Gu J. W., Zhang X. Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives // Organic Letters. 2015. Vol. 17. No. 21. pp. 5384-5387.
GOST all authors (up to 50)
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Gu J. W., Zhang X. Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives // Organic Letters. 2015. Vol. 17. No. 21. pp. 5384-5387.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.orglett.5b02739
UR - https://doi.org/10.1021/acs.orglett.5b02739
TI - Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives
T2 - Organic Letters
AU - Gu, Ji Wei
AU - Zhang, Xingang
PY - 2015
DA - 2015/10/26
PB - American Chemical Society (ACS)
SP - 5384-5387
IS - 21
VL - 17
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2015_Gu,
author = {Ji Wei Gu and Xingang Zhang},
title = {Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives},
journal = {Organic Letters},
year = {2015},
volume = {17},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.orglett.5b02739},
number = {21},
pages = {5384--5387},
doi = {10.1021/acs.orglett.5b02739}
}
Cite this
MLA
Copy
Gu, Ji Wei, and Xingang Zhang. “Palladium-Catalyzed Difluoroalkylation of Isocyanides: Access to Difluoroalkylated Phenanthridine Derivatives.” Organic Letters, vol. 17, no. 21, Oct. 2015, pp. 5384-5387. https://doi.org/10.1021/acs.orglett.5b02739.