Organic Letters

, том 17 , издание 21 , страницы 5472-5475

Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate

Тип публикации: Journal Article

Дата публикации: 2015-10-28

American Chemical Society (ACS)

Organic Letters

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SJR: 1.235

CiteScore: 8.7

Impact factor: 5

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.5b02835

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PubMed ID: 26507318

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Краткое описание

Commercially available palladium acetate often contains two major impurities, whose presence can impact the overall catalytic efficacy. This systematic study provides a comparison of the differences in catalytic activity of pure palladium acetate, Pd3(OAc)6, with the two impurities: Pd3(OAc)5(NO2) and polymeric [Pd(OAc)2]n in a variety of cross-coupling reactions. The solid state (13)C NMR spectra of all three compounds in conjunction with DFT calculations confirm their reported geometries.

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Carole W. A. et al. Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate // Organic Letters. 2015. Vol. 17. No. 21. pp. 5472-5475.

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Carole W. A., Bradley J., Sarwar M., Colacot T. J. Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate // Organic Letters. 2015. Vol. 17. No. 21. pp. 5472-5475.

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TY - JOUR

DO - 10.1021/acs.orglett.5b02835

UR - https://doi.org/10.1021/acs.orglett.5b02835

TI - Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate

T2 - Organic Letters

AU - Carole, William A

AU - Bradley, Jonathan

AU - Sarwar, Misbah

AU - Colacot, Thomas J

PY - 2015

DA - 2015/10/28

PB - American Chemical Society (ACS)

SP - 5472-5475

IS - 21

VL - 17

PMID - 26507318

SN - 1523-7060

SN - 1523-7052

ER -

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@article{2015_Carole,

author = {William A Carole and Jonathan Bradley and Misbah Sarwar and Thomas J Colacot},

title = {Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate},

journal = {Organic Letters},

year = {2015},

volume = {17},

publisher = {American Chemical Society (ACS)},

month = {oct},

url = {https://doi.org/10.1021/acs.orglett.5b02835},

number = {21},

pages = {5472--5475},

doi = {10.1021/acs.orglett.5b02835}

}

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Carole, William A., et al. “Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate.” Organic Letters, vol. 17, no. 21, Oct. 2015, pp. 5472-5475. https://doi.org/10.1021/acs.orglett.5b02835.