Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate
1
Johnson Matthey Catalysis and Chiral Technologies, 2001 Nolte Drive, West Deptford, New Jersey 08066, United States
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2
Johnson Matthey Technology Centre, Blounts Court Road, Sonning Common, Reading, West Berkshire RG4 9NH, United Kingdom
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Publication type: Journal Article
Publication date: 2015-10-28
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
26507318
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Commercially available palladium acetate often contains two major impurities, whose presence can impact the overall catalytic efficacy. This systematic study provides a comparison of the differences in catalytic activity of pure palladium acetate, Pd3(OAc)6, with the two impurities: Pd3(OAc)5(NO2) and polymeric [Pd(OAc)2]n in a variety of cross-coupling reactions. The solid state (13)C NMR spectra of all three compounds in conjunction with DFT calculations confirm their reported geometries.
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58
Total citations:
58
Citations from 2024:
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(15.52%)
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GOST
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Carole W. A. et al. Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate // Organic Letters. 2015. Vol. 17. No. 21. pp. 5472-5475.
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Carole W. A., Bradley J., Sarwar M., Colacot T. J. Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate // Organic Letters. 2015. Vol. 17. No. 21. pp. 5472-5475.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.5b02835
UR - https://doi.org/10.1021/acs.orglett.5b02835
TI - Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate
T2 - Organic Letters
AU - Carole, William A
AU - Bradley, Jonathan
AU - Sarwar, Misbah
AU - Colacot, Thomas J
PY - 2015
DA - 2015/10/28
PB - American Chemical Society (ACS)
SP - 5472-5475
IS - 21
VL - 17
PMID - 26507318
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Carole,
author = {William A Carole and Jonathan Bradley and Misbah Sarwar and Thomas J Colacot},
title = {Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate},
journal = {Organic Letters},
year = {2015},
volume = {17},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/acs.orglett.5b02835},
number = {21},
pages = {5472--5475},
doi = {10.1021/acs.orglett.5b02835}
}
Cite this
MLA
Copy
Carole, William A., et al. “Can Palladium Acetate Lose Its “Saltiness”? Catalytic Activities of the Impurities in Palladium Acetate.” Organic Letters, vol. 17, no. 21, Oct. 2015, pp. 5472-5475. https://doi.org/10.1021/acs.orglett.5b02835.