Reagents for Storage and Regeneration of Nonstabilized Azomethine Ylides: Spiroanthraceneoxazolidines
Тип публикации: Journal Article
Дата публикации: 2016-03-30
scimago Q1
wos Q1
БС1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
27028421
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
Nonstabilized azomethine ylides are easily trapped by anthraquinone to form stable spiro-oxazolidines, which have an unusual ability to undergo a cycloreversion in the presence of other dipolarophiles at 120-150 °C. All tested recycloadditions with carbonyl compounds and electron-poor alkenes occurred in moderate to high yields (41-92%). Moreover, increasing the reaction temperature to 210 °C made it possible to obtain adducts with low reactive dipolarophiles.
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Buev E. M., Moshkin V. S., Sosnovskikh V. Y. Reagents for Storage and Regeneration of Nonstabilized Azomethine Ylides: Spiroanthraceneoxazolidines // Organic Letters. 2016. Vol. 18. No. 8. pp. 1764-1767.
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Buev E. M., Moshkin V. S., Sosnovskikh V. Y. Reagents for Storage and Regeneration of Nonstabilized Azomethine Ylides: Spiroanthraceneoxazolidines // Organic Letters. 2016. Vol. 18. No. 8. pp. 1764-1767.
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TY - JOUR
DO - 10.1021/acs.orglett.6b00475
UR - https://doi.org/10.1021/acs.orglett.6b00475
TI - Reagents for Storage and Regeneration of Nonstabilized Azomethine Ylides: Spiroanthraceneoxazolidines
T2 - Organic Letters
AU - Buev, Evgeny M
AU - Moshkin, Vladimir S
AU - Sosnovskikh, Vyacheslav Ya.
PY - 2016
DA - 2016/03/30
PB - American Chemical Society (ACS)
SP - 1764-1767
IS - 8
VL - 18
PMID - 27028421
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2016_Buev,
author = {Evgeny M Buev and Vladimir S Moshkin and Vyacheslav Ya. Sosnovskikh},
title = {Reagents for Storage and Regeneration of Nonstabilized Azomethine Ylides: Spiroanthraceneoxazolidines},
journal = {Organic Letters},
year = {2016},
volume = {18},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acs.orglett.6b00475},
number = {8},
pages = {1764--1767},
doi = {10.1021/acs.orglett.6b00475}
}
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MLA
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Buev, Evgeny M., et al. “Reagents for Storage and Regeneration of Nonstabilized Azomethine Ylides: Spiroanthraceneoxazolidines.” Organic Letters, vol. 18, no. 8, Mar. 2016, pp. 1764-1767. https://doi.org/10.1021/acs.orglett.6b00475.