Regio- and Stereoselective Hydrosilylation of Unsymmetrical Alkynes Catalyzed by a Well-Defined, Low-Valent Cobalt Catalyst
Alejandro Rivera Hernández
1
,
Brendan J Fallon
1
,
Sandrine Ventre
1
,
Cedric Simon
1
,
Marie Hélène Tremblay
1
,
Geoffrey Gontard
1
,
Etienne Derat
1
,
Muriel Amatore
1
,
C Aubert
1
,
Marc Petit
1
Publication type: Journal Article
Publication date: 2016-08-23
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
27552360
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Herein, the use of a well-defined low-valent cobalt(I) catalyst [HCo(PMe3)4] capable of performing the highly regio- and stereoselective hydrosilylation of internal alkynes is reported. The reaction can be applied to a variety of hydrosilanes, symmetrical and unsymmetrical alkynes, giving in many cases a single hydrosilylation isomer. Experimental and theoretical studies suggest the key step to be a hydro-cobaltation and that the reaction proceeds through a classical Chalk-Harrod mechanism.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
6
7
|
|
|
Organic Letters
7 publications, 8.97%
|
|
|
ChemCatChem
7 publications, 8.97%
|
|
|
ACS Catalysis
6 publications, 7.69%
|
|
|
Chemistry - A European Journal
5 publications, 6.41%
|
|
|
Organometallics
4 publications, 5.13%
|
|
|
Angewandte Chemie - International Edition
3 publications, 3.85%
|
|
|
Angewandte Chemie
3 publications, 3.85%
|
|
|
Applied Organometallic Chemistry
3 publications, 3.85%
|
|
|
Chemistry - An Asian Journal
3 publications, 3.85%
|
|
|
Journal of the American Chemical Society
3 publications, 3.85%
|
|
|
Synthesis
3 publications, 3.85%
|
|
|
Russian Chemical Reviews
2 publications, 2.56%
|
|
|
Nature Communications
2 publications, 2.56%
|
|
|
Advanced Synthesis and Catalysis
2 publications, 2.56%
|
|
|
Chinese Journal of Chemistry
2 publications, 2.56%
|
|
|
New Journal of Chemistry
2 publications, 2.56%
|
|
|
Organic Chemistry Frontiers
2 publications, 2.56%
|
|
|
Green Chemistry
2 publications, 2.56%
|
|
|
Chemical Science
2 publications, 2.56%
|
|
|
Chemical Communications
2 publications, 2.56%
|
|
|
Catalysis Science and Technology
2 publications, 2.56%
|
|
|
Journal of Catalysis
1 publication, 1.28%
|
|
|
Journal of Organometallic Chemistry
1 publication, 1.28%
|
|
|
Tetrahedron Letters
1 publication, 1.28%
|
|
|
Asian Journal of Organic Chemistry
1 publication, 1.28%
|
|
|
Chemical Reviews
1 publication, 1.28%
|
|
|
Journal of Organic Chemistry
1 publication, 1.28%
|
|
|
RSC Advances
1 publication, 1.28%
|
|
|
Topics in Organometallic Chemistry
1 publication, 1.28%
|
|
|
1
2
3
4
5
6
7
|
Publishers
|
5
10
15
20
25
30
|
|
|
Wiley
30 publications, 38.46%
|
|
|
American Chemical Society (ACS)
22 publications, 28.21%
|
|
|
Royal Society of Chemistry (RSC)
13 publications, 16.67%
|
|
|
Elsevier
5 publications, 6.41%
|
|
|
Springer Nature
3 publications, 3.85%
|
|
|
Georg Thieme Verlag KG
3 publications, 3.85%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 2.56%
|
|
|
5
10
15
20
25
30
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
78
Total citations:
78
Citations from 2024:
17
(21.79%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Rivera Hernández A. et al. Regio- and Stereoselective Hydrosilylation of Unsymmetrical Alkynes Catalyzed by a Well-Defined, Low-Valent Cobalt Catalyst // Organic Letters. 2016. Vol. 18. No. 17. pp. 4242-4245.
GOST all authors (up to 50)
Copy
Rivera Hernández A., Fallon B. J., Ventre S., Simon C., Tremblay M. H., Gontard G., Derat E., Amatore M., Aubert C., Petit M. Regio- and Stereoselective Hydrosilylation of Unsymmetrical Alkynes Catalyzed by a Well-Defined, Low-Valent Cobalt Catalyst // Organic Letters. 2016. Vol. 18. No. 17. pp. 4242-4245.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.6b01987
UR - https://doi.org/10.1021/acs.orglett.6b01987
TI - Regio- and Stereoselective Hydrosilylation of Unsymmetrical Alkynes Catalyzed by a Well-Defined, Low-Valent Cobalt Catalyst
T2 - Organic Letters
AU - Rivera Hernández, Alejandro
AU - Fallon, Brendan J
AU - Ventre, Sandrine
AU - Simon, Cedric
AU - Tremblay, Marie Hélène
AU - Gontard, Geoffrey
AU - Derat, Etienne
AU - Amatore, Muriel
AU - Aubert, C
AU - Petit, Marc
PY - 2016
DA - 2016/08/23
PB - American Chemical Society (ACS)
SP - 4242-4245
IS - 17
VL - 18
PMID - 27552360
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Rivera Hernández,
author = {Alejandro Rivera Hernández and Brendan J Fallon and Sandrine Ventre and Cedric Simon and Marie Hélène Tremblay and Geoffrey Gontard and Etienne Derat and Muriel Amatore and C Aubert and Marc Petit},
title = {Regio- and Stereoselective Hydrosilylation of Unsymmetrical Alkynes Catalyzed by a Well-Defined, Low-Valent Cobalt Catalyst},
journal = {Organic Letters},
year = {2016},
volume = {18},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.orglett.6b01987},
number = {17},
pages = {4242--4245},
doi = {10.1021/acs.orglett.6b01987}
}
Cite this
MLA
Copy
Rivera Hernández, Alejandro, et al. “Regio- and Stereoselective Hydrosilylation of Unsymmetrical Alkynes Catalyzed by a Well-Defined, Low-Valent Cobalt Catalyst.” Organic Letters, vol. 18, no. 17, Aug. 2016, pp. 4242-4245. https://doi.org/10.1021/acs.orglett.6b01987.