Organic Letters

, том 18 , издание 24 , страницы 6324-6327

Pd-Catalyzed Spirocyclization via C–H Activation and Benzyne Insertion

Тип публикации: Journal Article

Дата публикации: 2016-12-01

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

white level БС1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.6b03213

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PubMed ID: 27978695

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Краткое описание

A palladium-catalyzed spirocyclization forming spirooxindoles and spirodihydrobenzofurans has been achieved. Mechanistic studies suggest that the transformation proceeds through sequential carbopalladation, C-H activation, and benzyne insertion. Both classes of spirocycles have been synthesized in good to excellent yields, and the procedure is readily scalable.

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Yoon H. et al. Pd-Catalyzed Spirocyclization via C–H Activation and Benzyne Insertion // Organic Letters. 2016. Vol. 18. No. 24. pp. 6324-6327.

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Yoon H., Lossouarn A., Landau F., Petrone D. A. Pd-Catalyzed Spirocyclization via C–H Activation and Benzyne Insertion // Organic Letters. 2016. Vol. 18. No. 24. pp. 6324-6327.

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TY - JOUR

DO - 10.1021/acs.orglett.6b03213

UR - https://doi.org/10.1021/acs.orglett.6b03213

TI - Pd-Catalyzed Spirocyclization via C–H Activation and Benzyne Insertion

T2 - Organic Letters

AU - Yoon, Hyung

AU - Lossouarn, Alexis

AU - Landau, Felicitas

AU - Petrone, David A.

PY - 2016

DA - 2016/12/01

PB - American Chemical Society (ACS)

SP - 6324-6327

IS - 24

VL - 18

PMID - 27978695

SN - 1523-7060

SN - 1523-7052

ER -

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@article{2016_Yoon,

author = {Hyung Yoon and Alexis Lossouarn and Felicitas Landau and David A. Petrone},

title = {Pd-Catalyzed Spirocyclization via C–H Activation and Benzyne Insertion},

journal = {Organic Letters},

year = {2016},

volume = {18},

publisher = {American Chemical Society (ACS)},

month = {dec},

url = {https://doi.org/10.1021/acs.orglett.6b03213},

number = {24},

pages = {6324--6327},

doi = {10.1021/acs.orglett.6b03213}

}

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Yoon, Hyung, et al. “Pd-Catalyzed Spirocyclization via C–H Activation and Benzyne Insertion.” Organic Letters, vol. 18, no. 24, Dec. 2016, pp. 6324-6327. https://doi.org/10.1021/acs.orglett.6b03213.