Radical Silyldifluoromethylation of Electron-Deficient Alkenes
Publication type: Journal Article
Publication date: 2017-05-25
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
28541046
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A reaction of bromo- and iododifluoromethyl-substituted silanes with electron-deficient alkenes in the presence of an N-heterocyclic carbene borane complex is described. The reaction is performed under irradiation with light-emitting diodes and proceeds via a radical chain mechanism. The resulting products, the functionalized silicon reagents, can undergo chemoselective transformations involving either the silyldifluoromethyl fragment or the functional group.
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Metrics
60
Total citations:
60
Citations from 2024:
21
(35%)
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BibTex |
MLA
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GOST
Copy
Supranovich V. I. et al. Radical Silyldifluoromethylation of Electron-Deficient Alkenes // Organic Letters. 2017. Vol. 19. No. 12. pp. 3215-3218.
GOST all authors (up to 50)
Copy
Supranovich V. I., Levin V. V., Struchkova M. I., Korlyukov A., Dilman A. D. Radical Silyldifluoromethylation of Electron-Deficient Alkenes // Organic Letters. 2017. Vol. 19. No. 12. pp. 3215-3218.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.7b01334
UR - https://doi.org/10.1021/acs.orglett.7b01334
TI - Radical Silyldifluoromethylation of Electron-Deficient Alkenes
T2 - Organic Letters
AU - Supranovich, Vyacheslav I
AU - Levin, Vitalij V
AU - Struchkova, Marina I.
AU - Korlyukov, Alexander
AU - Dilman, Alexander D
PY - 2017
DA - 2017/05/25
PB - American Chemical Society (ACS)
SP - 3215-3218
IS - 12
VL - 19
PMID - 28541046
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Supranovich,
author = {Vyacheslav I Supranovich and Vitalij V Levin and Marina I. Struchkova and Alexander Korlyukov and Alexander D Dilman},
title = {Radical Silyldifluoromethylation of Electron-Deficient Alkenes},
journal = {Organic Letters},
year = {2017},
volume = {19},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.orglett.7b01334},
number = {12},
pages = {3215--3218},
doi = {10.1021/acs.orglett.7b01334}
}
Cite this
MLA
Copy
Supranovich, Vyacheslav I., et al. “Radical Silyldifluoromethylation of Electron-Deficient Alkenes.” Organic Letters, vol. 19, no. 12, May. 2017, pp. 3215-3218. https://doi.org/10.1021/acs.orglett.7b01334.
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