(Z)-Selective Hydrosilylation of Terminal Alkynes with HSiMe(OSiMe3)2 Catalyzed by a Ruthenium Complex Containing an N-Heterocyclic Carbene
Publication type: Journal Article
Publication date: 2017-09-08
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
28885855
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The N-heterocyclic-carbene-ligated ruthenium complex [RuHCl(CO)(H2IMes)(PCy3)] exhibits high catalytic activity for the (Z)-selective hydrosilylation of various terminal alkynes with 1,1,1,3,5,5,5-heptamethyltrisiloxane (HSiMe(OSiMe3)2). The stereoretentive derivatization of the (Z)-alkenylsiloxanes allows the synthesis of biologically active compounds, e.g. potent antitumor agents and inhibitors for induced-NO synthase.
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41
Total citations:
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Citations from 2024:
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(24.39%)
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Mutoh Y., Mohara Y., SAITO S. (Z)-Selective Hydrosilylation of Terminal Alkynes with HSiMe(OSiMe3)2 Catalyzed by a Ruthenium Complex Containing an N-Heterocyclic Carbene // Organic Letters. 2017. Vol. 19. No. 19. pp. 5204-5207.
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Mutoh Y., Mohara Y., SAITO S. (Z)-Selective Hydrosilylation of Terminal Alkynes with HSiMe(OSiMe3)2 Catalyzed by a Ruthenium Complex Containing an N-Heterocyclic Carbene // Organic Letters. 2017. Vol. 19. No. 19. pp. 5204-5207.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acs.orglett.7b02477
UR - https://doi.org/10.1021/acs.orglett.7b02477
TI - (Z)-Selective Hydrosilylation of Terminal Alkynes with HSiMe(OSiMe3)2 Catalyzed by a Ruthenium Complex Containing an N-Heterocyclic Carbene
T2 - Organic Letters
AU - Mutoh, Yuichiro
AU - Mohara, Yusei
AU - SAITO, Shinichi
PY - 2017
DA - 2017/09/08
PB - American Chemical Society (ACS)
SP - 5204-5207
IS - 19
VL - 19
PMID - 28885855
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Mutoh,
author = {Yuichiro Mutoh and Yusei Mohara and Shinichi SAITO},
title = {(Z)-Selective Hydrosilylation of Terminal Alkynes with HSiMe(OSiMe3)2 Catalyzed by a Ruthenium Complex Containing an N-Heterocyclic Carbene},
journal = {Organic Letters},
year = {2017},
volume = {19},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.orglett.7b02477},
number = {19},
pages = {5204--5207},
doi = {10.1021/acs.orglett.7b02477}
}
Cite this
MLA
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Mutoh, Yuichiro, et al. “(Z)-Selective Hydrosilylation of Terminal Alkynes with HSiMe(OSiMe3)2 Catalyzed by a Ruthenium Complex Containing an N-Heterocyclic Carbene.” Organic Letters, vol. 19, no. 19, Sep. 2017, pp. 5204-5207. https://doi.org/10.1021/acs.orglett.7b02477.