A Bench-Stable, Single-Component Precatalyst for Silyl–Heck Reactions
Publication type: Journal Article
Publication date: 2017-09-29
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
28960083
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Studies of the silyl-Heck reaction aimed at identifying active palladium complexes have revealed a new species that is formed in situ. This complex has been identified as the palladium iodide dimer, [(JessePhos)PdI2]2, which has been found to be a competent single-component precatalyst for the silyl-Heck reaction. This complex is easily prepared and is temperature, moisture, and air stable. Additionally, this precatalyst provides higher activity and greater reproducibility compared to previous systems.
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28
Total citations:
28
Citations from 2024:
7
(25%)
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GOST
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Krause S. B. et al. A Bench-Stable, Single-Component Precatalyst for Silyl–Heck Reactions // Organic Letters. 2017. Vol. 19. No. 20. pp. 5641-5644.
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Krause S. B., Mcatee J. R., Yap G. P. A., WATSON D. P. A Bench-Stable, Single-Component Precatalyst for Silyl–Heck Reactions // Organic Letters. 2017. Vol. 19. No. 20. pp. 5641-5644.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.7b02807
UR - https://doi.org/10.1021/acs.orglett.7b02807
TI - A Bench-Stable, Single-Component Precatalyst for Silyl–Heck Reactions
T2 - Organic Letters
AU - Krause, Sarah B
AU - Mcatee, Jesse R
AU - Yap, Glenn P. A.
AU - WATSON, DONALD P.
PY - 2017
DA - 2017/09/29
PB - American Chemical Society (ACS)
SP - 5641-5644
IS - 20
VL - 19
PMID - 28960083
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Krause,
author = {Sarah B Krause and Jesse R Mcatee and Glenn P. A. Yap and DONALD P. WATSON},
title = {A Bench-Stable, Single-Component Precatalyst for Silyl–Heck Reactions},
journal = {Organic Letters},
year = {2017},
volume = {19},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.orglett.7b02807},
number = {20},
pages = {5641--5644},
doi = {10.1021/acs.orglett.7b02807}
}
Cite this
MLA
Copy
Krause, Sarah B., et al. “A Bench-Stable, Single-Component Precatalyst for Silyl–Heck Reactions.” Organic Letters, vol. 19, no. 20, Sep. 2017, pp. 5641-5644. https://doi.org/10.1021/acs.orglett.7b02807.