Enantioselective Trapping of Oxonium Ylides by 3-Hydroxyisoindolinones via a Formal SN1 Pathway for Construction of Contiguous Quaternary Stereocenters
Publication type: Journal Article
Publication date: 2018-01-30
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
29380603
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
An enantioselective Rh(II)/chiral phosphoric acid co-catalyzed three-component reaction via trapping of oxonium ylides with 3-hydroxyisoindolinones by a formal SN1 pathway is described. This reaction allows for the efficient synthesis of isoindolinone derivatives with two contiguous quaternary stereogenic centers in high yields (up to 93%) with excellent enantioselectivities and moderate diastereoselectivities under mild reaction conditions.
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62
Total citations:
62
Citations from 2024:
10
(16%)
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GOST
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Kang Z. et al. Enantioselective Trapping of Oxonium Ylides by 3-Hydroxyisoindolinones via a Formal SN1 Pathway for Construction of Contiguous Quaternary Stereocenters // Organic Letters. 2018. Vol. 20. No. 4. pp. 983-986.
GOST all authors (up to 50)
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Kang Z., Zhang D., Shou J., Hu W. Enantioselective Trapping of Oxonium Ylides by 3-Hydroxyisoindolinones via a Formal SN1 Pathway for Construction of Contiguous Quaternary Stereocenters // Organic Letters. 2018. Vol. 20. No. 4. pp. 983-986.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.7b03916
UR - https://doi.org/10.1021/acs.orglett.7b03916
TI - Enantioselective Trapping of Oxonium Ylides by 3-Hydroxyisoindolinones via a Formal SN1 Pathway for Construction of Contiguous Quaternary Stereocenters
T2 - Organic Letters
AU - Kang, Zhenghui
AU - Zhang, Dan
AU - Shou, Jiayi
AU - Hu, Wenhao
PY - 2018
DA - 2018/01/30
PB - American Chemical Society (ACS)
SP - 983-986
IS - 4
VL - 20
PMID - 29380603
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Kang,
author = {Zhenghui Kang and Dan Zhang and Jiayi Shou and Wenhao Hu},
title = {Enantioselective Trapping of Oxonium Ylides by 3-Hydroxyisoindolinones via a Formal SN1 Pathway for Construction of Contiguous Quaternary Stereocenters},
journal = {Organic Letters},
year = {2018},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.orglett.7b03916},
number = {4},
pages = {983--986},
doi = {10.1021/acs.orglett.7b03916}
}
Cite this
MLA
Copy
Kang, Zhenghui, et al. “Enantioselective Trapping of Oxonium Ylides by 3-Hydroxyisoindolinones via a Formal SN1 Pathway for Construction of Contiguous Quaternary Stereocenters.” Organic Letters, vol. 20, no. 4, Jan. 2018, pp. 983-986. https://doi.org/10.1021/acs.orglett.7b03916.