Formal Insertion of Thioketenes into Donor–Acceptor Cyclopropanes by Lewis Acid Catalysis
Тип публикации: Journal Article
Дата публикации: 2018-01-18
scimago Q1
wos Q1
БС1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5
ISSN: 15237060, 15237052
PubMed ID:
29345137
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
Donor-acceptor cyclopropanes were reacted under Lewis acid catalysis with 3-thioxocyclobutanones as surrogates for disubstituted thioketenes. A broad scope of 2-substituted tetrahydrothiophenes with a semicyclic double bond was obtained under mild conditions with high functional group tolerance and in excellent yield. A sequence of a formal [3 + 2]-cycloaddition followed by the subsequent release of disubstituted ketene is postulated as the mechanism.
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ГОСТ |
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MLA
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ГОСТ
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Augustin A. U. et al. Formal Insertion of Thioketenes into Donor–Acceptor Cyclopropanes by Lewis Acid Catalysis // Organic Letters. 2018. Vol. 20. No. 3. pp. 820-823.
ГОСТ со всеми авторами (до 50)
Скопировать
Augustin A. U., Busse M., Peter B. Jones (2) P., Werz D. B. Formal Insertion of Thioketenes into Donor–Acceptor Cyclopropanes by Lewis Acid Catalysis // Organic Letters. 2018. Vol. 20. No. 3. pp. 820-823.
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RIS
Скопировать
TY - JOUR
DO - 10.1021/acs.orglett.7b03961
UR - https://doi.org/10.1021/acs.orglett.7b03961
TI - Formal Insertion of Thioketenes into Donor–Acceptor Cyclopropanes by Lewis Acid Catalysis
T2 - Organic Letters
AU - Augustin, André U
AU - Busse, Marius
AU - Peter B. Jones (2), PA
AU - Werz, Daniel B.
PY - 2018
DA - 2018/01/18
PB - American Chemical Society (ACS)
SP - 820-823
IS - 3
VL - 20
PMID - 29345137
SN - 1523-7060
SN - 1523-7052
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2018_Augustin,
author = {André U Augustin and Marius Busse and PA Peter B. Jones (2) and Daniel B. Werz},
title = {Formal Insertion of Thioketenes into Donor–Acceptor Cyclopropanes by Lewis Acid Catalysis},
journal = {Organic Letters},
year = {2018},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/acs.orglett.7b03961},
number = {3},
pages = {820--823},
doi = {10.1021/acs.orglett.7b03961}
}
Цитировать
MLA
Скопировать
Augustin, André U., et al. “Formal Insertion of Thioketenes into Donor–Acceptor Cyclopropanes by Lewis Acid Catalysis.” Organic Letters, vol. 20, no. 3, Jan. 2018, pp. 820-823. https://doi.org/10.1021/acs.orglett.7b03961.