Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation
Publication type: Journal Article
Publication date: 2018-05-15
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
29763322
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A visible light-promoted hydrosilylation of alkynes has been explored and achieved using 1 mol % organic dye Eosin Y as the photocatalyst and a catalytic amount of thiol as the radical quencher. The corresponding alkenylsilanes were provided with high regio- and stereoselectivites in the reactions of various terminal and internal alkynes. The experimental evidence shows that the reaction is preferentially initiated by a single electron transfer process, and a photoredox pathway is suggested.
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74
Total citations:
74
Citations from 2024:
16
(21.62%)
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GOST
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Zhu J. et al. Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation // Organic Letters. 2018. Vol. 20. No. 11. pp. 3174-3178.
GOST all authors (up to 50)
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Zhu J., Cui W. C., WANG S., Yao Z. Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation // Organic Letters. 2018. Vol. 20. No. 11. pp. 3174-3178.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.8b00909
UR - https://doi.org/10.1021/acs.orglett.8b00909
TI - Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation
T2 - Organic Letters
AU - Zhu, Jing
AU - Cui, Wei Chen
AU - WANG, SHAOZHONG
AU - Yao, Zhu-Jun
PY - 2018
DA - 2018/05/15
PB - American Chemical Society (ACS)
SP - 3174-3178
IS - 11
VL - 20
PMID - 29763322
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Zhu,
author = {Jing Zhu and Wei Chen Cui and SHAOZHONG WANG and Zhu-Jun Yao},
title = {Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation},
journal = {Organic Letters},
year = {2018},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.orglett.8b00909},
number = {11},
pages = {3174--3178},
doi = {10.1021/acs.orglett.8b00909}
}
Cite this
MLA
Copy
Zhu, Jing, et al. “Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation.” Organic Letters, vol. 20, no. 11, May. 2018, pp. 3174-3178. https://doi.org/10.1021/acs.orglett.8b00909.