Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation
Тип публикации: Journal Article
Дата публикации: 2018-05-15
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.007
CiteScore: 7.7
Impact factor: 4.7
ISSN: 15237060, 15237052
PubMed ID:
29763322
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
A visible light-promoted hydrosilylation of alkynes has been explored and achieved using 1 mol % organic dye Eosin Y as the photocatalyst and a catalytic amount of thiol as the radical quencher. The corresponding alkenylsilanes were provided with high regio- and stereoselectivites in the reactions of various terminal and internal alkynes. The experimental evidence shows that the reaction is preferentially initiated by a single electron transfer process, and a photoredox pathway is suggested.
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ГОСТ
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Zhu J. et al. Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation // Organic Letters. 2018. Vol. 20. No. 11. pp. 3174-3178.
ГОСТ со всеми авторами (до 50)
Скопировать
Zhu J., Cui W. C., WANG S., Yao Z. Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation // Organic Letters. 2018. Vol. 20. No. 11. pp. 3174-3178.
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RIS
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TY - JOUR
DO - 10.1021/acs.orglett.8b00909
UR - https://doi.org/10.1021/acs.orglett.8b00909
TI - Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation
T2 - Organic Letters
AU - Zhu, Jing
AU - Cui, Wei Chen
AU - WANG, SHAOZHONG
AU - Yao, Zhu-Jun
PY - 2018
DA - 2018/05/15
PB - American Chemical Society (ACS)
SP - 3174-3178
IS - 11
VL - 20
PMID - 29763322
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex (до 50 авторов)
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@article{2018_Zhu,
author = {Jing Zhu and Wei Chen Cui and SHAOZHONG WANG and Zhu-Jun Yao},
title = {Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation},
journal = {Organic Letters},
year = {2018},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acs.orglett.8b00909},
number = {11},
pages = {3174--3178},
doi = {10.1021/acs.orglett.8b00909}
}
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MLA
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Zhu, Jing, et al. “Radical Hydrosilylation of Alkynes Catalyzed by Eosin Y and Thiol under Visible Light Irradiation.” Organic Letters, vol. 20, no. 11, May. 2018, pp. 3174-3178. https://doi.org/10.1021/acs.orglett.8b00909.
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