An NNN-Pincer-Cobalt Complex Catalyzed Highly Markovnikov-Selective Alkyne Hydrosilylation
Publication type: Journal Article
Publication date: 2018-09-26
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
30256120
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A new NNN pincer (amine-pyridine-imine, API) cobalt complex, which is bench-stable and is applicable for the highly efficient and regioselective hydrosilylation of terminal alkynes, is developed. A broad set of α-vinylsilanes was successfully synthesized in good to high yields with up to 98/2 Markovnikov regioselectivity. This protocol can be readily scaled up for gram-scale synthesis and demonstrates the most efficient cobalt-catalyzed hydrosilylation of alkynes with turnover frequencies as high as 126 720 h-1 to date.
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67
Total citations:
67
Citations from 2024:
19
(28.36%)
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MLA
Cite this
GOST
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Zhang S. et al. An NNN-Pincer-Cobalt Complex Catalyzed Highly Markovnikov-Selective Alkyne Hydrosilylation // Organic Letters. 2018. Vol. 20. No. 19. pp. 6265-6269.
GOST all authors (up to 50)
Copy
Zhang S., Ibrahim J. J., Yang Y. An NNN-Pincer-Cobalt Complex Catalyzed Highly Markovnikov-Selective Alkyne Hydrosilylation // Organic Letters. 2018. Vol. 20. No. 19. pp. 6265-6269.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.orglett.8b02746
UR - https://doi.org/10.1021/acs.orglett.8b02746
TI - An NNN-Pincer-Cobalt Complex Catalyzed Highly Markovnikov-Selective Alkyne Hydrosilylation
T2 - Organic Letters
AU - Zhang, Shaochun
AU - Ibrahim, Jessica Juweriah
AU - Yang, Yong
PY - 2018
DA - 2018/09/26
PB - American Chemical Society (ACS)
SP - 6265-6269
IS - 19
VL - 20
PMID - 30256120
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Zhang,
author = {Shaochun Zhang and Jessica Juweriah Ibrahim and Yong Yang},
title = {An NNN-Pincer-Cobalt Complex Catalyzed Highly Markovnikov-Selective Alkyne Hydrosilylation},
journal = {Organic Letters},
year = {2018},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.orglett.8b02746},
number = {19},
pages = {6265--6269},
doi = {10.1021/acs.orglett.8b02746}
}
Cite this
MLA
Copy
Zhang, Shaochun, et al. “An NNN-Pincer-Cobalt Complex Catalyzed Highly Markovnikov-Selective Alkyne Hydrosilylation.” Organic Letters, vol. 20, no. 19, Sep. 2018, pp. 6265-6269. https://doi.org/10.1021/acs.orglett.8b02746.