Visible-Light-Initiated Manganese-Catalyzed E-Selective Hydrosilylation and Hydrogermylation of Alkynes
Тип публикации: Journal Article
Дата публикации: 2019-04-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.007
CiteScore: 8.7
Impact factor: 5
ISSN: 15237060, 15237052
PubMed ID:
30931573
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
Manganese-photocatalyzed activation of the Si-H bond in silanes for the hydrosilylation of alkynes has been developed. The mild protocol operates efficiently with high regioselectivity ( anti-Markovnikov) and stereoselectivity ( Z/ E ratio ranges from 92:8 to >99:1), providing a wide range of Z-vinylsilanes in high yields. Moreover, visible-light-induced manganese-catalyzed activation of the Ge-H bond for E-selective alkyne hydrogermylation is reported for the first time.
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ГОСТ
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Hao L. et al. Visible-Light-Initiated Manganese-Catalyzed E-Selective Hydrosilylation and Hydrogermylation of Alkynes // Organic Letters. 2019. Vol. 21. No. 8. pp. 2750-2754.
ГОСТ со всеми авторами (до 50)
Скопировать
Hao L., Ji Y. X., Wang R. H., Tan N., Zhang B. Visible-Light-Initiated Manganese-Catalyzed E-Selective Hydrosilylation and Hydrogermylation of Alkynes // Organic Letters. 2019. Vol. 21. No. 8. pp. 2750-2754.
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RIS
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TY - JOUR
DO - 10.1021/acs.orglett.9b00701
UR - https://doi.org/10.1021/acs.orglett.9b00701
TI - Visible-Light-Initiated Manganese-Catalyzed E-Selective Hydrosilylation and Hydrogermylation of Alkynes
T2 - Organic Letters
AU - Hao, Liang
AU - Ji, Yun Xing
AU - Wang, Rui Han
AU - Tan, Ninghua
AU - Zhang, Bo
PY - 2019
DA - 2019/04/01
PB - American Chemical Society (ACS)
SP - 2750-2754
IS - 8
VL - 21
PMID - 30931573
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex (до 50 авторов)
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@article{2019_Hao,
author = {Liang Hao and Yun Xing Ji and Rui Han Wang and Ninghua Tan and Bo Zhang},
title = {Visible-Light-Initiated Manganese-Catalyzed E-Selective Hydrosilylation and Hydrogermylation of Alkynes},
journal = {Organic Letters},
year = {2019},
volume = {21},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acs.orglett.9b00701},
number = {8},
pages = {2750--2754},
doi = {10.1021/acs.orglett.9b00701}
}
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MLA
Скопировать
Hao, Liang, et al. “Visible-Light-Initiated Manganese-Catalyzed E-Selective Hydrosilylation and Hydrogermylation of Alkynes.” Organic Letters, vol. 21, no. 8, Apr. 2019, pp. 2750-2754. https://doi.org/10.1021/acs.orglett.9b00701.
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