Organic Letters

, volume 21 , issue 11 , pages 4271-4274

Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst

Vyacheslav I Supranovich ¹

Vitalij V Levin ¹

Alexander D Dilman ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation |

Publication type: Journal Article

Publication date: 2019-05-13

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5.0

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.9b01450

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PubMed ID: 31081641

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Abstract

A method for the radical addition toward N-tosylimines based on light promoted C-H activation by tetrabutylammonium decatungstate is described. The reaction proceeds under irradiation using 400 nm light emitting diodes in conventional glassware. The method can be applied for alkylations (cycloalkanes, ethers, dimethylformamide) and acylation (primary aliphatic aldehydes) of both aromatic and aliphatic N-tosylimines.

Found

4 citations

Dilman Alexander

DSc in Chemistry, associate member of the Russian Academy of Sciences

208 publications, 5 167 citations, 152 reviews

h-index: 39

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Organic Chemistry

1 citation

Levin Oleg

DSc in Chemistry

145 publications, 1 893 citations, 115 reviews

h-index: 25

Sirius University of Science and Technology

Saint Petersburg State University

Research interests

Electrochemistry

Materials Science

1 citation

Mulina Olga

PhD in Chemistry

33 publications, 648 citations, 4 reviews

h-index: 14

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Electrosynthesis

Free radicals

1 citation

Segida Oleg

16 publications, 254 citations

h-index: 8

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

1 citation

Krylov Igor

PhD in Chemistry

81 publications, 1 903 citations, 18 reviews

h-index: 26

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Research interests

Green chemistry

Organic Chemistry

Organic electrochemistry

Organic synthesis

Photochemistry

Plant protection

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Supranovich V. I., Levin V. V., Dilman A. D. Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst // Organic Letters. 2019. Vol. 21. No. 11. pp. 4271-4274.

GOST all authors (up to 50) Copy

Supranovich V. I., Levin V. V., Dilman A. D. Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst // Organic Letters. 2019. Vol. 21. No. 11. pp. 4271-4274.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.orglett.9b01450

UR - https://doi.org/10.1021/acs.orglett.9b01450

TI - Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst

T2 - Organic Letters

AU - Supranovich, Vyacheslav I

AU - Levin, Vitalij V

AU - Dilman, Alexander D

PY - 2019

DA - 2019/05/13

PB - American Chemical Society (ACS)

SP - 4271-4274

IS - 11

VL - 21

PMID - 31081641

SN - 1523-7060

SN - 1523-7052

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Supranovich,

author = {Vyacheslav I Supranovich and Vitalij V Levin and Alexander D Dilman},

title = {Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst},

journal = {Organic Letters},

year = {2019},

volume = {21},

publisher = {American Chemical Society (ACS)},

month = {may},

url = {https://doi.org/10.1021/acs.orglett.9b01450},

number = {11},

pages = {4271--4274},

doi = {10.1021/acs.orglett.9b01450}

}

MLA

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MLA Copy

Supranovich, Vyacheslav I., et al. “Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst.” Organic Letters, vol. 21, no. 11, May. 2019, pp. 4271-4274. https://doi.org/10.1021/acs.orglett.9b01450.

Publisher

American Chemical Society (ACS)

Journal

Organic Letters

scimago Q1

wos Q1

SJR

1.235

CiteScore

8.7

Impact factor

5.0

ISSN

15237060 (Print)

15237052 (Electronic)

Profiles

Alexander D Dilman