Organic Letters

, том 21 , издание 15 , страницы 5817-5822

Arylation of Aldehydes To Directly Form Ketones via Tandem Nickel Catalysis.

Тип публикации: Journal Article

Дата публикации: 2019-07-16

American Chemical Society (ACS)

Organic Letters

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SJR: 1.007

CiteScore: 8.7

Impact factor: 5

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.9b01782

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PubMed ID: 31310560

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Краткое описание

A nickel-catalyzed arylation of both aliphatic and aromatic aldehydes proceeds with air-stable (hetero)arylboronic acids, with an exceptionally wide substrate scope. The neutral condition tolerates acidic hydrogen and sensitive polar groups and also preserves α-stereocenters of some chiral aldehydes. Interestingly, this nickel(0) catalysis does not follow common 1,2-insertion of arylmetal species to aldehydes and β-hydrogen elimination.

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Lei C. et al. Arylation of Aldehydes To Directly Form Ketones via Tandem Nickel Catalysis. // Organic Letters. 2019. Vol. 21. No. 15. pp. 5817-5822.

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Lei C., Zhu D., Tangcueco V. I. T., Zhou J. Arylation of Aldehydes To Directly Form Ketones via Tandem Nickel Catalysis. // Organic Letters. 2019. Vol. 21. No. 15. pp. 5817-5822.

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TY - JOUR

DO - 10.1021/acs.orglett.9b01782

UR - https://doi.org/10.1021/acs.orglett.9b01782

TI - Arylation of Aldehydes To Directly Form Ketones via Tandem Nickel Catalysis.

T2 - Organic Letters

AU - Lei, Chuanhu

AU - Zhu, Daoyong

AU - Tangcueco, Vicente Iii Tiu

AU - Zhou, Jianrong

PY - 2019

DA - 2019/07/16

PB - American Chemical Society (ACS)

SP - 5817-5822

IS - 15

VL - 21

PMID - 31310560

SN - 1523-7060

SN - 1523-7052

ER -

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@article{2019_Lei,

author = {Chuanhu Lei and Daoyong Zhu and Vicente Iii Tiu Tangcueco and Jianrong Zhou},

title = {Arylation of Aldehydes To Directly Form Ketones via Tandem Nickel Catalysis.},

journal = {Organic Letters},

year = {2019},

volume = {21},

publisher = {American Chemical Society (ACS)},

month = {jul},

url = {https://doi.org/10.1021/acs.orglett.9b01782},

number = {15},

pages = {5817--5822},

doi = {10.1021/acs.orglett.9b01782}

}

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Lei, Chuanhu, et al. “Arylation of Aldehydes To Directly Form Ketones via Tandem Nickel Catalysis..” Organic Letters, vol. 21, no. 15, Jul. 2019, pp. 5817-5822. https://doi.org/10.1021/acs.orglett.9b01782.

Издатель

American Chemical Society (ACS)

Журнал

Organic Letters

SCImago Q1

Tоп 10% SCImago

WOS Q1

БС1