Organic Letters

, volume 21 , issue 14 , pages 5767-5772

Bidentate Geometry-Constrained Iminopyridyl Ligands in Cobalt Catalysis: Highly Markovnikov-Selective Hydrosilylation of Alkynes

Zhijian Zong ¹

Qianwen Yu ¹

Nan Sun ¹

Baoxiang Hu ¹

Zhenlu Shen ¹

Xinquan Hu ¹

Liqun Jin ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310032, P. R. China |

State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, the Chinese Academy of Sciences, Lanzhou 730000, P. R. China |

Publication type: Journal Article

Publication date: 2019-07-10

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5.0

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.9b02254

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PubMed ID: 31290677

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Abstract

Reported herein is a well-defined bidentate geometry-constrained iminopyridyl cobalt complex for an efficient and highly Markovnikov-selective hydrosilylation of alkynes, featuring a broad substrate scope including aromatic/heteroaromatic/aliphatic alkynes and primary/secondary silanes. TON is up to 4950. The kinetic study together with structures clearly revealed that the ligand played the key effect on the efficiency.

Found

1 citation

Cherkasov Anton

245 publications, 3 660 citations

h-index: 30

G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Research interests

Coordination Chemistry

1 citation

Lyssenko Konstantin

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DSc in Chemistry, professor

898 publications, 15 180 citations, 2 reviews

h-index: 50

Lomonosov Moscow State University

National Research University Higher School of Economics

Research interests

Supramolecular chemistry

1 citation

Obaedkov Anatoliy

PhD in Chemistry

56 publications, 464 citations

h-index: 11

G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

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Zong Z. et al. Bidentate Geometry-Constrained Iminopyridyl Ligands in Cobalt Catalysis: Highly Markovnikov-Selective Hydrosilylation of Alkynes // Organic Letters. 2019. Vol. 21. No. 14. pp. 5767-5772.

GOST all authors (up to 50) Copy

Zong Z., Yu Q., Sun N., Hu B., Shen Z., Hu X., Jin L. Bidentate Geometry-Constrained Iminopyridyl Ligands in Cobalt Catalysis: Highly Markovnikov-Selective Hydrosilylation of Alkynes // Organic Letters. 2019. Vol. 21. No. 14. pp. 5767-5772.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/acs.orglett.9b02254

UR - https://doi.org/10.1021/acs.orglett.9b02254

TI - Bidentate Geometry-Constrained Iminopyridyl Ligands in Cobalt Catalysis: Highly Markovnikov-Selective Hydrosilylation of Alkynes

T2 - Organic Letters

AU - Zong, Zhijian

AU - Yu, Qianwen

AU - Sun, Nan

AU - Hu, Baoxiang

AU - Shen, Zhenlu

AU - Hu, Xinquan

AU - Jin, Liqun

PY - 2019

DA - 2019/07/10

PB - American Chemical Society (ACS)

SP - 5767-5772

IS - 14

VL - 21

PMID - 31290677

SN - 1523-7060

SN - 1523-7052

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2019_Zong,

author = {Zhijian Zong and Qianwen Yu and Nan Sun and Baoxiang Hu and Zhenlu Shen and Xinquan Hu and Liqun Jin},

title = {Bidentate Geometry-Constrained Iminopyridyl Ligands in Cobalt Catalysis: Highly Markovnikov-Selective Hydrosilylation of Alkynes},

journal = {Organic Letters},

year = {2019},

volume = {21},

publisher = {American Chemical Society (ACS)},

month = {jul},

url = {https://doi.org/10.1021/acs.orglett.9b02254},

number = {14},

pages = {5767--5772},

doi = {10.1021/acs.orglett.9b02254}

}

MLA

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MLA Copy

Zong, Zhijian, et al. “Bidentate Geometry-Constrained Iminopyridyl Ligands in Cobalt Catalysis: Highly Markovnikov-Selective Hydrosilylation of Alkynes.” Organic Letters, vol. 21, no. 14, Jul. 2019, pp. 5767-5772. https://doi.org/10.1021/acs.orglett.9b02254.

Publisher

American Chemical Society (ACS)

Journal

Organic Letters

scimago Q1

wos Q1

SJR

1.235

CiteScore

8.7

Impact factor

5.0

ISSN

15237060 (Print)

15237052 (Electronic)