Organic Letters

, том 22 , издание 1 , страницы 204-208

Equatorial Sulfur Atoms in Bambusurils Spawn Cavity Collapse

Тип публикации: Journal Article

Дата публикации: 2019-12-17

American Chemical Society (ACS)

Organic Letters

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SJR: 1.007

CiteScore: 7.7

Impact factor: 4.7

ISSN: 15237060, 15237052

DOI: 10.1021/acs.orglett.9b04166

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PubMed ID: 31846336

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

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This study confirms the hypothesis that bambusurils (BUs) with equatorial sulfur atoms cannot assume an anion-binding jigger conformation due to strong intramolecular van der Waals attractive interactions. NMR, X-ray crystallography, and computation with newly synthesized eq-semithio-BU[4] and ax-semiaza-eq-semithio-BU[4]s indicate that they all assume compact conformations. Intramolecular distances and a torsional angle serve as reliable indicators of the conformation of any BU. Chemoselective alkylation at the peripheral (equatorial) thiourea functions provides a convenient entry to novel hetero-BUs.

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Journal of Organic Chemistry	Journal of Organic Chemistry, 2, 15.38% Journal of Organic Chemistry 2 публикации, 15.38%
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Chemistry of Heterocyclic Compounds	Chemistry of Heterocyclic Compounds, 1, 7.69% Chemistry of Heterocyclic Compounds 1 публикация, 7.69%
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Tetrahedron Letters	Tetrahedron Letters, 1, 7.69% Tetrahedron Letters 1 публикация, 7.69%
Organic Chemistry Frontiers	Organic Chemistry Frontiers, 1, 7.69% Organic Chemistry Frontiers 1 публикация, 7.69%
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Mondal P. et al. Equatorial Sulfur Atoms in Bambusurils Spawn Cavity Collapse // Organic Letters. 2019. Vol. 22. No. 1. pp. 204-208.

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Mondal P., Solel E., Mitra S., Keinan E., Reany O. Equatorial Sulfur Atoms in Bambusurils Spawn Cavity Collapse // Organic Letters. 2019. Vol. 22. No. 1. pp. 204-208.

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TY - JOUR

DO - 10.1021/acs.orglett.9b04166

UR - https://doi.org/10.1021/acs.orglett.9b04166

TI - Equatorial Sulfur Atoms in Bambusurils Spawn Cavity Collapse

T2 - Organic Letters

AU - Mondal, Pravat

AU - Solel, Ephrath

AU - Mitra, Shubhanjan

AU - Keinan, Ehud

AU - Reany, O.

PY - 2019

DA - 2019/12/17

PB - American Chemical Society (ACS)

SP - 204-208

IS - 1

VL - 22

PMID - 31846336

SN - 1523-7060

SN - 1523-7052

ER -

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@article{2019_Mondal,

author = {Pravat Mondal and Ephrath Solel and Shubhanjan Mitra and Ehud Keinan and O. Reany},

title = {Equatorial Sulfur Atoms in Bambusurils Spawn Cavity Collapse},

journal = {Organic Letters},

year = {2019},

volume = {22},

publisher = {American Chemical Society (ACS)},

month = {dec},

url = {https://doi.org/10.1021/acs.orglett.9b04166},

number = {1},

pages = {204--208},

doi = {10.1021/acs.orglett.9b04166}

}

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Mondal, Pravat, et al. “Equatorial Sulfur Atoms in Bambusurils Spawn Cavity Collapse.” Organic Letters, vol. 22, no. 1, Dec. 2019, pp. 204-208. https://doi.org/10.1021/acs.orglett.9b04166.

Издатель

American Chemical Society (ACS)

Журнал

Organic Letters

SCImago Q1

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WOS Q1

БС1