Layered Chirality Relay Model in Rh(I)-Mediated Enantioselective C–Si Bond Activation: A Theoretical Study
Тип публикации: Journal Article
Дата публикации: 2020-02-03
scimago Q1
wos Q1
БС1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5
ISSN: 15237060, 15237052
PubMed ID:
32011898
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
A three-layer chirality relay model is proposed for Rh(I)-mediated enantioselective siletane activation. A chiral ligand in the back layer controls the position of the alkyne-coordinated metal center in the middle layer, which then provides a chiral environment for the incoming substrate at the front layer. A two-dimensional contour map analysis further clarified this model.
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ГОСТ
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Liu S. et al. Layered Chirality Relay Model in Rh(I)-Mediated Enantioselective C–Si Bond Activation: A Theoretical Study // Organic Letters. 2020. Vol. 22. No. 6. pp. 2124-2128.
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Liu S., Zhang T., Zhu L., Liu F., Bai R., Lan Yu. Layered Chirality Relay Model in Rh(I)-Mediated Enantioselective C–Si Bond Activation: A Theoretical Study // Organic Letters. 2020. Vol. 22. No. 6. pp. 2124-2128.
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TY - JOUR
DO - 10.1021/acs.orglett.9b04636
UR - https://doi.org/10.1021/acs.orglett.9b04636
TI - Layered Chirality Relay Model in Rh(I)-Mediated Enantioselective C–Si Bond Activation: A Theoretical Study
T2 - Organic Letters
AU - Liu, Shihan
AU - Zhang, Tao
AU - Zhu, Lei
AU - Liu, Fenru
AU - Bai, Ruopeng
AU - Lan, Yu
PY - 2020
DA - 2020/02/03
PB - American Chemical Society (ACS)
SP - 2124-2128
IS - 6
VL - 22
PMID - 32011898
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2020_Liu,
author = {Shihan Liu and Tao Zhang and Lei Zhu and Fenru Liu and Ruopeng Bai and Yu Lan},
title = {Layered Chirality Relay Model in Rh(I)-Mediated Enantioselective C–Si Bond Activation: A Theoretical Study},
journal = {Organic Letters},
year = {2020},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acs.orglett.9b04636},
number = {6},
pages = {2124--2128},
doi = {10.1021/acs.orglett.9b04636}
}
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MLA
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Liu, Shihan, et al. “Layered Chirality Relay Model in Rh(I)-Mediated Enantioselective C–Si Bond Activation: A Theoretical Study.” Organic Letters, vol. 22, no. 6, Feb. 2020, pp. 2124-2128. https://doi.org/10.1021/acs.orglett.9b04636.
