ACS applied materials & interfaces, volume 8, issue 34, pages 22526-22533

Site-Specific Ligand Interactions Favor the Tetragonal Distortion of PbS Nanocrystal Superlattices

J. Novák ^{1, 2}

R Banerjee ³

Andreas Kornowski ⁴

Maciej Jankowski ⁵

Alexander André ⁶

Horst Weller ⁴

Frank Schreiber ^{7, 8}

Marcus Scheele ^{6, 8}

Hide authors affiliations Show authors affiliations: 8 affiliations

Central European Institute of Technology, Masaryk University, Kamenice 5, CZ-62500 Brno, Czech Republic |

Department of Condensed Matter Physics, Masaryk University, Kotlářská 2, CZ-61137 Brno, Czech Republic |

Department of Physics, Indian Institute of Technology Gandhinagar, Palaj, Gandhinagar 382355, India |

⁴

Institute of Physical Chemistry and The Hamburg Centre for Ultrafast Imaging, University of Hamburg, Grindelallee 117, 20146 Hamburg, Germany |

⁵

Beamline ID03, European Synchrotron Radiation Facility, Grenoble F-38043, France |

⁶

Institute of Physical and Theoretical Chemistry, University of Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany |

⁷

Institute of Applied Physics, University of Tübingen, Auf der Morgenstelle 10, 72076 Tübingen, Germany |

⁸

Center for Light−Matter Interaction, Sensors & Analytics, University of Tübingen, Auf der Morgenstelle 15, 72076 Tübingen, Germany |

Publication type: Journal Article

Publication date: 2016-08-17

American Chemical Society (ACS)

Journal: ACS applied materials & interfaces

Quartile SCImago

Quartile WOS

Impact factor: 9.5

ISSN: 19448244, 19448252

DOI: 10.1021/acsami.6b06989

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General Materials Science

Abstract

We analyze the structure and morphology of mesocrystalline, body-centered tetragonal (bct) superlattices of PbS nanocrystals functionalized with oleic acid. On the basis of combined scattering and real space imaging, we derive a three-dimensional (3D) model of the superlattice and show that the bct structure benefits from a balanced combination of {100}PbS-{100}PbS and {111}PbS-{111}PbS interactions between neighboring layers of nanocrystals, which uniquely stabilizes this structure. These interactions are enabled by the coaxial alignment of the atomic lattices of PbS with the superlattice. In addition, we find that this preferential orientation is already weakly present within isolated monolayers. By adding excess oleic acid to the nanocrystal solution, tetragonal distortion is suppressed, and we observe assembly into a bilayered hexagonal lattice reminiscent of a honeycomb with grain sizes of several micrometers.

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Citations by journals

	1 2 3
Nano Letters	Nano Letters, 3, 8.82% Nano Letters 3 publications, 8.82%
Nanoscale	Nanoscale, 3, 8.82% Nanoscale 3 publications, 8.82%
Small	Small, 2, 5.88% Small 2 publications, 5.88%
Journal of the American Chemical Society	Journal of the American Chemical Society, 2, 5.88% Journal of the American Chemical Society 2 publications, 5.88%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 5.88% ACS applied materials & interfaces 2 publications, 5.88%
Journal of Physical Chemistry C	Journal of Physical Chemistry C, 2, 5.88% Journal of Physical Chemistry C 2 publications, 5.88%
Journal of Physical Chemistry Letters	Journal of Physical Chemistry Letters, 2, 5.88% Journal of Physical Chemistry Letters 2 publications, 5.88%
ACS Nano	ACS Nano, 2, 5.88% ACS Nano 2 publications, 5.88%
Chemistry of Materials	Chemistry of Materials, 2, 5.88% Chemistry of Materials 2 publications, 5.88%
Chemical Communications	Chemical Communications, 2, 5.88% Chemical Communications 2 publications, 5.88%
Materials	Materials, 1, 2.94% Materials 1 publication, 2.94%
Nature Materials	Nature Materials, 1, 2.94% Nature Materials 1 publication, 2.94%
International Journal of Hydrogen Energy	International Journal of Hydrogen Energy, 1, 2.94% International Journal of Hydrogen Energy 1 publication, 2.94%
Advanced Science	Advanced Science, 1, 2.94% Advanced Science 1 publication, 2.94%
Advanced Materials	Advanced Materials, 1, 2.94% Advanced Materials 1 publication, 2.94%
Particle and Particle Systems Characterization	Particle and Particle Systems Characterization, 1, 2.94% Particle and Particle Systems Characterization 1 publication, 2.94%
ACS Applied Nano Materials	ACS Applied Nano Materials, 1, 2.94% ACS Applied Nano Materials 1 publication, 2.94%
Nanoscale Horizons	Nanoscale Horizons, 1, 2.94% Nanoscale Horizons 1 publication, 2.94%
Chemical Society Reviews	Chemical Society Reviews, 1, 2.94% Chemical Society Reviews 1 publication, 2.94%
Microscopy and Microanalysis	Microscopy and Microanalysis, 1, 2.94% Microscopy and Microanalysis 1 publication, 2.94%
Dalton Transactions	Dalton Transactions, 1, 2.94% Dalton Transactions 1 publication, 2.94%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 2.94% Russian Chemical Reviews 1 publication, 2.94%
	1 2 3

Citations by publishers

	2 4 6 8 10 12 14 16
American Chemical Society (ACS)	American Chemical Society (ACS), 16, 47.06% American Chemical Society (ACS) 16 publications, 47.06%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 8, 23.53% Royal Society of Chemistry (RSC) 8 publications, 23.53%
Wiley	Wiley, 5, 14.71% Wiley 5 publications, 14.71%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 2.94% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 2.94%
Springer Nature	Springer Nature, 1, 2.94% Springer Nature 1 publication, 2.94%
Elsevier	Elsevier, 1, 2.94% Elsevier 1 publication, 2.94%
Oxford University Press	Oxford University Press, 1, 2.94% Oxford University Press 1 publication, 2.94%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.94% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.94%
	2 4 6 8 10 12 14 16

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Novák J. et al. Site-Specific Ligand Interactions Favor the Tetragonal Distortion of PbS Nanocrystal Superlattices // ACS applied materials & interfaces. 2016. Vol. 8. No. 34. pp. 22526-22533.

GOST all authors (up to 50) Copy

Novák J., Banerjee R., Kornowski A., Jankowski M., André A., Weller H., Schreiber F., Scheele M. Site-Specific Ligand Interactions Favor the Tetragonal Distortion of PbS Nanocrystal Superlattices // ACS applied materials & interfaces. 2016. Vol. 8. No. 34. pp. 22526-22533.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/acsami.6b06989

UR - https://doi.org/10.1021/acsami.6b06989

TI - Site-Specific Ligand Interactions Favor the Tetragonal Distortion of PbS Nanocrystal Superlattices

T2 - ACS applied materials & interfaces

AU - Kornowski, Andreas

AU - André, Alexander

AU - Novák, J.

AU - Banerjee, R

AU - Jankowski, Maciej

AU - Weller, Horst

AU - Schreiber, Frank

AU - Scheele, Marcus

PY - 2016

DA - 2016/08/17 00:00:00

PB - American Chemical Society (ACS)

SP - 22526-22533

IS - 34

VL - 8

SN - 1944-8244

SN - 1944-8252

ER -

BibTex |

Cite this

BibTex Copy

@article{2016_Novák,

author = {Andreas Kornowski and Alexander André and J. Novák and R Banerjee and Maciej Jankowski and Horst Weller and Frank Schreiber and Marcus Scheele},

title = {Site-Specific Ligand Interactions Favor the Tetragonal Distortion of PbS Nanocrystal Superlattices},

journal = {ACS applied materials & interfaces},

year = {2016},

volume = {8},

publisher = {American Chemical Society (ACS)},

month = {aug},

url = {https://doi.org/10.1021/acsami.6b06989},

number = {34},

pages = {22526--22533},

doi = {10.1021/acsami.6b06989}

}

MLA

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MLA Copy

Novák, J., et al. “Site-Specific Ligand Interactions Favor the Tetragonal Distortion of PbS Nanocrystal Superlattices.” ACS applied materials & interfaces, vol. 8, no. 34, Aug. 2016, pp. 22526-22533. https://doi.org/10.1021/acsami.6b06989.

Found error?

Publisher

American Chemical Society (ACS)

Journal

ACS applied materials & interfaces

Quartile SCImago

Quartile WOS

Impact factor

9.5

ISSN

19448244 (Print)
19448252 (Electronic)