Zeolite-like Metal-Organic Framework (MOF) Encaged Pt(II)-Porphyrin for Anion-Selective Sensing.
Publication type: Journal Article
Publication date: 2018-03-26
scimago Q1
wos Q1
SJR: 1.921
CiteScore: 14.5
Impact factor: 8.2
ISSN: 19448244, 19448252
PubMed ID:
29578682
General Materials Science
Abstract
The selectivity and sensitivity of sensors are of great interest to the materials chemistry community, and a lot of effort is now devoted to improving these characteristics. More specifically, the selective sensing of anions is one of the largest challenges impeding the sensing-research area due to their similar physical and chemical behaviors. In this work, platinum-metalated porphyrin (Pt(II)TMPyP) was successfully encapsulated in a rho-type zeolite-like metal-organic framework (rho-ZMOF) and applied for anion-selective sensing. The sensing activity and selectivity of the MOF-encaged Pt(II)TMPyP for various anions in aqueous and methanolic media were compared to that of the free (nonencapsulated) Pt(II)TMPyP. While the photoinduced triplet-state electron transfer of Pt(II)TMPyP showed a very low detection limit for anions with no selectivity, the Pt(II)TMPyP encapsulated in the rho-ZMOF framework possessed a unique chemical structure to overcome such limitations. This new approach has the potential for use in other complex sensing applications, including biosensors, which require ion selectivity.
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Total citations:
87
Citations from 2024:
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(22.99%)
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Masih D. et al. Zeolite-like Metal-Organic Framework (MOF) Encaged Pt(II)-Porphyrin for Anion-Selective Sensing. // ACS applied materials & interfaces. 2018. Vol. 10. No. 14. pp. 11399-11405.
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Masih D., Chernikova V., Shekhah O., Eddaoudi M., Mohammed O. Zeolite-like Metal-Organic Framework (MOF) Encaged Pt(II)-Porphyrin for Anion-Selective Sensing. // ACS applied materials & interfaces. 2018. Vol. 10. No. 14. pp. 11399-11405.
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TY - JOUR
DO - 10.1021/acsami.7b19282
UR - https://doi.org/10.1021/acsami.7b19282
TI - Zeolite-like Metal-Organic Framework (MOF) Encaged Pt(II)-Porphyrin for Anion-Selective Sensing.
T2 - ACS applied materials & interfaces
AU - Masih, Dilshad
AU - Chernikova, Valeriya
AU - Shekhah, Osama
AU - Eddaoudi, Mohamed
AU - Mohammed, Omar
PY - 2018
DA - 2018/03/26
PB - American Chemical Society (ACS)
SP - 11399-11405
IS - 14
VL - 10
PMID - 29578682
SN - 1944-8244
SN - 1944-8252
ER -
Cite this
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@article{2018_Masih,
author = {Dilshad Masih and Valeriya Chernikova and Osama Shekhah and Mohamed Eddaoudi and Omar Mohammed},
title = {Zeolite-like Metal-Organic Framework (MOF) Encaged Pt(II)-Porphyrin for Anion-Selective Sensing.},
journal = {ACS applied materials & interfaces},
year = {2018},
volume = {10},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acsami.7b19282},
number = {14},
pages = {11399--11405},
doi = {10.1021/acsami.7b19282}
}
Cite this
MLA
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Masih, Dilshad, et al. “Zeolite-like Metal-Organic Framework (MOF) Encaged Pt(II)-Porphyrin for Anion-Selective Sensing..” ACS applied materials & interfaces, vol. 10, no. 14, Mar. 2018, pp. 11399-11405. https://doi.org/10.1021/acsami.7b19282.