Effect of Ti3AlC2 MAX Phase on Structure and Properties of Resultant Ti3C2Tx MXene
Publication type: Journal Article
Publication date: 2019-05-13
scimago Q1
wos Q2
SJR: 1.121
CiteScore: 8.1
Impact factor: 5.5
ISSN: 25740970
General Materials Science
Abstract
Ti3C2Tx MXene is an attractive two-dimensional (2D) material for a wide variety of applications; however, measured properties vary widely from study to study. A potential factor to the property differences relates to variability in the MAX phase precursors. To illustrate this, Ti3AlC2, the precursor for Ti3C2Tx MXene, was synthesized using three carbon sources (graphite, carbon lampblack, and titanium carbide (TiC)) at 1650 °C for 2 h. Thermal analysis was utilized to examine the reaction mechanism, indicating that the three carbon sources experience different reaction pathways. The Ti3AlC2 MAX powders were then converted into Ti3C2Tx MXene and delaminated. The products revealed differences with respect to the lateral flake size, chemical composition, chemical stability in deionized water, and electrical conductivity. Graphite-produced Ti3C2Tx showed the highest conductivity (∼4400 S/cm) and is the most stable (time constant of 10.1 days), while TiC-produced MXene has comparable conductivity (∼3480 S/cm),...
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Total citations:
345
Citations from 2024:
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(47.54%)
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Shuck C. E. et al. Effect of Ti3AlC2 MAX Phase on Structure and Properties of Resultant Ti3C2Tx MXene // ACS Applied Nano Materials. 2019. Vol. 2. No. 6. pp. 3368-3376.
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Shuck C. E., Han M., Maleski K., Hantanasirisakul K., Kim S. J., Choi J., Reil W. E. B., Gogotsi Y. Effect of Ti3AlC2 MAX Phase on Structure and Properties of Resultant Ti3C2Tx MXene // ACS Applied Nano Materials. 2019. Vol. 2. No. 6. pp. 3368-3376.
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TY - JOUR
DO - 10.1021/acsanm.9b00286
UR - https://doi.org/10.1021/acsanm.9b00286
TI - Effect of Ti3AlC2 MAX Phase on Structure and Properties of Resultant Ti3C2Tx MXene
T2 - ACS Applied Nano Materials
AU - Shuck, Christopher Eugene
AU - Han, Meikang
AU - Maleski, Kathleen
AU - Hantanasirisakul, Kanit
AU - Kim, Seon Joon
AU - Choi, Junghoon
AU - Reil, William E B
AU - Gogotsi, Yury
PY - 2019
DA - 2019/05/13
PB - American Chemical Society (ACS)
SP - 3368-3376
IS - 6
VL - 2
SN - 2574-0970
ER -
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@article{2019_Shuck,
author = {Christopher Eugene Shuck and Meikang Han and Kathleen Maleski and Kanit Hantanasirisakul and Seon Joon Kim and Junghoon Choi and William E B Reil and Yury Gogotsi},
title = {Effect of Ti3AlC2 MAX Phase on Structure and Properties of Resultant Ti3C2Tx MXene},
journal = {ACS Applied Nano Materials},
year = {2019},
volume = {2},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acsanm.9b00286},
number = {6},
pages = {3368--3376},
doi = {10.1021/acsanm.9b00286}
}
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Shuck, Christopher Eugene, et al. “Effect of Ti3AlC2 MAX Phase on Structure and Properties of Resultant Ti3C2Tx MXene.” ACS Applied Nano Materials, vol. 2, no. 6, May. 2019, pp. 3368-3376. https://doi.org/10.1021/acsanm.9b00286.