Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling
1
Worldwide
Research and Development, Pfizer
Inc., Eastern Point Road, Groton, Connecticut 06340, United States
|
Publication type: Journal Article
Publication date: 2015-04-21
scimago Q1
wos Q1
SJR: 3.782
CiteScore: 19.5
Impact factor: 13.1
ISSN: 21555435
General Chemistry
Catalysis
Abstract
The synthesis of NiCl(o-tolyl)(TMEDA) (3; TMEDA = tetramethylethylenediamine) and its application in coupling reactions is described. In combination with a suitable ligand, precatalyst 3 was applied to a wide range of transformations, such as Suzuki, amination, Kumada, Negishi, Heck, borylation, and reductive coupling. Yields of products obtained with 3 are equal or superior to those obtained with common Ni sources such as Ni(cod)2 (1) and NiCl2(dme) (2). Importantly, and unlike 1, complex 3 is stable for months in air as a solid, which eliminates the need for a glovebox and greatly facilitates the reaction setup. Thus, complex 3 is the first highly versatile Ni source that combines the broad applicability of 1 with the air stability of 2.
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Metrics
120
Total citations:
120
Citations from 2025:
7
(5.83%)
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MLA
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GOST
Copy
Magano J., Monfette S. Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling // ACS Catalysis. 2015. Vol. 5. No. 5. pp. 3120-3123.
GOST all authors (up to 50)
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Magano J., Monfette S. Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling // ACS Catalysis. 2015. Vol. 5. No. 5. pp. 3120-3123.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acscatal.5b00498
UR - https://doi.org/10.1021/acscatal.5b00498
TI - Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling
T2 - ACS Catalysis
AU - Magano, Javier
AU - Monfette, Sebastien
PY - 2015
DA - 2015/04/21
PB - American Chemical Society (ACS)
SP - 3120-3123
IS - 5
VL - 5
SN - 2155-5435
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Magano,
author = {Javier Magano and Sebastien Monfette},
title = {Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling},
journal = {ACS Catalysis},
year = {2015},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/acscatal.5b00498},
number = {5},
pages = {3120--3123},
doi = {10.1021/acscatal.5b00498}
}
Cite this
MLA
Copy
Magano, Javier, and Sebastien Monfette. “Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling.” ACS Catalysis, vol. 5, no. 5, Apr. 2015, pp. 3120-3123. https://doi.org/10.1021/acscatal.5b00498.