Hydrogenative Carbon Dioxide Reduction Catalyzed by Mononuclear Ruthenium Polypyridyl Complexes: Discerning between Electronic and Steric Effects
Takashi Ono
1
,
Shuanglin Qu
2
,
Carolina Gimbert-Suriñach
1
,
Michelle A Johnson
2
,
Daniel J Marell
2
,
Jordi Benet-Buchholz
1
,
A. Llobet
1, 3
1
Publication type: Journal Article
Publication date: 2017-08-09
scimago Q1
wos Q1
SJR: 3.782
CiteScore: 19.5
Impact factor: 13.1
ISSN: 21555435
General Chemistry
Catalysis
Abstract
The preparation and isolation of a family of Ru–Cl complexes containing the deprotonated anionic tridentate meridional ligand (1Z,3Z)-N1,N3-di(pyridin-2-yl)isoindoline-1,3-diimine (Hbid) and 1,3-di(2-pyridyl)benzene) (Hdpb), namely, [Ru(bid)(acac)Cl], 1d, [Ru(bid)(6,6′-Me2-bpy)Cl], 1e, trans-[Ru(bid)(py)2Cl], 2, [Ru(dpb)(bpy)Cl], 3a, and [Ru(dpb)(4,4′-(COOEt)2-bpy)Cl], 3b, are reported. All these complexes have been thoroughly characterized in solution by NMR spectroscopy and for 1d and 1e by single-crystal X-ray diffraction analysis. Furthermore, the redox properties of all complexes have been investigated using cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The capacity of the various complexes to catalyze hydrogenative CO2 reduction was also investigated. Compound 1e is the best catalyst, achieving initial turnover frequencies above 1000 h–1. Kinetic analysis identifies a relationship between Ru(III/II) couple redox potentials and initial turnover frequencies. Finally, DFT calculatio...
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Ono T. et al. Hydrogenative Carbon Dioxide Reduction Catalyzed by Mononuclear Ruthenium Polypyridyl Complexes: Discerning between Electronic and Steric Effects // ACS Catalysis. 2017. Vol. 7. No. 9. pp. 5932-5940.
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Ono T., Qu S., Gimbert-Suriñach C., Johnson M. A., Marell D. J., Benet-Buchholz J., Cramer C. S., Llobet A. Hydrogenative Carbon Dioxide Reduction Catalyzed by Mononuclear Ruthenium Polypyridyl Complexes: Discerning between Electronic and Steric Effects // ACS Catalysis. 2017. Vol. 7. No. 9. pp. 5932-5940.
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RIS
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TY - JOUR
DO - 10.1021/acscatal.7b00603
UR - https://doi.org/10.1021/acscatal.7b00603
TI - Hydrogenative Carbon Dioxide Reduction Catalyzed by Mononuclear Ruthenium Polypyridyl Complexes: Discerning between Electronic and Steric Effects
T2 - ACS Catalysis
AU - Ono, Takashi
AU - Qu, Shuanglin
AU - Gimbert-Suriñach, Carolina
AU - Johnson, Michelle A
AU - Marell, Daniel J
AU - Benet-Buchholz, Jordi
AU - Cramer, Christopher S.
AU - Llobet, A.
PY - 2017
DA - 2017/08/09
PB - American Chemical Society (ACS)
SP - 5932-5940
IS - 9
VL - 7
SN - 2155-5435
ER -
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BibTex (up to 50 authors)
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@article{2017_Ono,
author = {Takashi Ono and Shuanglin Qu and Carolina Gimbert-Suriñach and Michelle A Johnson and Daniel J Marell and Jordi Benet-Buchholz and Christopher S. Cramer and A. Llobet},
title = {Hydrogenative Carbon Dioxide Reduction Catalyzed by Mononuclear Ruthenium Polypyridyl Complexes: Discerning between Electronic and Steric Effects},
journal = {ACS Catalysis},
year = {2017},
volume = {7},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acscatal.7b00603},
number = {9},
pages = {5932--5940},
doi = {10.1021/acscatal.7b00603}
}
Cite this
MLA
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Ono, Takashi, et al. “Hydrogenative Carbon Dioxide Reduction Catalyzed by Mononuclear Ruthenium Polypyridyl Complexes: Discerning between Electronic and Steric Effects.” ACS Catalysis, vol. 7, no. 9, Aug. 2017, pp. 5932-5940. https://doi.org/10.1021/acscatal.7b00603.