ACS Catalysis, volume 7, issue 6, pages 3860-3863
Access to Biorenewable Polycarbonates with Unusual Glass-Transition Temperature (Tg) Modulation
Publication type: Journal Article
Publication date: 2017-05-02
General Chemistry
Catalysis
Abstract
A sequential and mild approach toward the synthesis of poly(limonene)dicarbonate (PLDC) has been developed using readily available limonene oxide (LO) and CO2 as renewable reagents and an air-stable Al(III) complex as catalyst for the alkene-rich poly(limonene)carbonate (PLC). The developed sequence allows for the stepwise construction of different PLDC polymers, using PLC as a synthetic intermediate with molecular weights of up to 15.3 kg/mol and tunable glass-transition temperature (Tg) values of up to an unprecedented 180 °C using a commercially available mixture of cis/trans (+)-LO.
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Kindermann N. et al. Access to Biorenewable Polycarbonates with Unusual Glass-Transition Temperature (Tg) Modulation // ACS Catalysis. 2017. Vol. 7. No. 6. pp. 3860-3863.
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Kindermann N., Cristòfol À., Kleij A. W. Access to Biorenewable Polycarbonates with Unusual Glass-Transition Temperature (Tg) Modulation // ACS Catalysis. 2017. Vol. 7. No. 6. pp. 3860-3863.
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TY - JOUR
DO - 10.1021/acscatal.7b00770
UR - https://doi.org/10.1021/acscatal.7b00770
TI - Access to Biorenewable Polycarbonates with Unusual Glass-Transition Temperature (Tg) Modulation
T2 - ACS Catalysis
AU - Kindermann, Nicole
AU - Cristòfol, Àlex
AU - Kleij, Arjan W
PY - 2017
DA - 2017/05/02
PB - American Chemical Society (ACS)
SP - 3860-3863
IS - 6
VL - 7
SN - 2155-5435
ER -
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@article{2017_Kindermann,
author = {Nicole Kindermann and Àlex Cristòfol and Arjan W Kleij},
title = {Access to Biorenewable Polycarbonates with Unusual Glass-Transition Temperature (Tg) Modulation},
journal = {ACS Catalysis},
year = {2017},
volume = {7},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acscatal.7b00770},
number = {6},
pages = {3860--3863},
doi = {10.1021/acscatal.7b00770}
}
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Kindermann, Nicole, et al. “Access to Biorenewable Polycarbonates with Unusual Glass-Transition Temperature (Tg) Modulation.” ACS Catalysis, vol. 7, no. 6, May. 2017, pp. 3860-3863. https://doi.org/10.1021/acscatal.7b00770.