ACS Catalysis, volume 7, issue 6, pages 4115-4121
Rational and Then Serendipitous Formation of Aza Analogues of Hoveyda-Type Catalysts Containing a Chelating Ester Group Leading to a Polymerization Catalyst Family
Stefan Czarnocki
1
,
Izabela Czeluśniak
2
,
Tomasz Olszewski
3
,
Maura Malinska
1
,
Krzysztof Woźniak
1
,
Publication type: Journal Article
Publication date: 2017-05-16
Journal:
ACS Catalysis
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 12.9
ISSN: 21555435, 21555435
General Chemistry
Catalysis
Abstract
Analogues of the well-known Hoveyda–Grubbs catalyst bearing both a chelating ester function and a chelating nitrogen atom were obtained. These complexes behave differently depending on the character of the chelating amine. Complexes containing a secondary amine underwent unexpected spontaneous oxidation of the amine group, leading to the Schiff base analogues. In contrast, complexes containing a tertiary amine were prone to intramolecular cyclization in the presence of a base (Et3N). Probing the activity of such (pre)catalysts in ring-closing metathesis reactions (RCMs) revealed their dormant character and excellent thermo-switchability. In particular, complexes bearing an iminium nitrogen fragment were found to be very useful in a delayed ring-opening metathesis polymerization (ROMP) and were therefore commercialized.
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Citations by publishers
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7
8
9
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American Chemical Society (ACS)
9 publications, 33.33%
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5 publications, 18.52%
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3 publications, 11.11%
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3 publications, 11.11%
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2 publications, 7.41%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Czarnocki S. et al. Rational and Then Serendipitous Formation of Aza Analogues of Hoveyda-Type Catalysts Containing a Chelating Ester Group Leading to a Polymerization Catalyst Family // ACS Catalysis. 2017. Vol. 7. No. 6. pp. 4115-4121.
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Czarnocki S., Czeluśniak I., Olszewski T., Malinska M., Woźniak K., Grela K. Rational and Then Serendipitous Formation of Aza Analogues of Hoveyda-Type Catalysts Containing a Chelating Ester Group Leading to a Polymerization Catalyst Family // ACS Catalysis. 2017. Vol. 7. No. 6. pp. 4115-4121.
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TY - JOUR
DO - 10.1021/acscatal.7b00843
UR - https://doi.org/10.1021/acscatal.7b00843
TI - Rational and Then Serendipitous Formation of Aza Analogues of Hoveyda-Type Catalysts Containing a Chelating Ester Group Leading to a Polymerization Catalyst Family
T2 - ACS Catalysis
AU - Czeluśniak, Izabela
AU - Woźniak, Krzysztof
AU - Grela, Karol
AU - Czarnocki, Stefan
AU - Olszewski, Tomasz
AU - Malinska, Maura
PY - 2017
DA - 2017/05/16 00:00:00
PB - American Chemical Society (ACS)
SP - 4115-4121
IS - 6
VL - 7
SN - 2155-5435
SN - 2155-5435
ER -
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@article{2017_Czarnocki,
author = {Izabela Czeluśniak and Krzysztof Woźniak and Karol Grela and Stefan Czarnocki and Tomasz Olszewski and Maura Malinska},
title = {Rational and Then Serendipitous Formation of Aza Analogues of Hoveyda-Type Catalysts Containing a Chelating Ester Group Leading to a Polymerization Catalyst Family},
journal = {ACS Catalysis},
year = {2017},
volume = {7},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acscatal.7b00843},
number = {6},
pages = {4115--4121},
doi = {10.1021/acscatal.7b00843}
}
Cite this
MLA
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Czarnocki, Stefan, et al. “Rational and Then Serendipitous Formation of Aza Analogues of Hoveyda-Type Catalysts Containing a Chelating Ester Group Leading to a Polymerization Catalyst Family.” ACS Catalysis, vol. 7, no. 6, May. 2017, pp. 4115-4121. https://doi.org/10.1021/acscatal.7b00843.