ACS Catalysis, volume 7, issue 9, pages 6347-6351
Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide
Publication type: Journal Article
Publication date: 2017-08-23
General Chemistry
Catalysis
Abstract
Mn(I)-PNP pincer catalyzed sequential one-pot homogeneous CO2 hydrogenation to CH3OH by molecular H2 is demonstrated. The hydrogenation consists of two parts—N-formylation of an amine utilizing CO2 and H2, and subsequent formamide reduction to CH3OH, regenerating the amine in the process. A reported air-stable and well-defined Mn-PNP pincer complex was found active for the catalysis of both steps. CH3OH yields up to 84% and 71% (w.r.t amine) were obtained, when benzylamine and morpholine were used as amines, respectively; and a TON of up to 36 was observed. In our opinion, this study represents an important development in the nascent field of base-metal-catalyzed homogeneous CO2 hydrogenation to CH3OH.
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Kar S. et al. Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide // ACS Catalysis. 2017. Vol. 7. No. 9. pp. 6347-6351.
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Kar S., Goeppert A., Kothandaraman J., Surya Prakash G. K. Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide // ACS Catalysis. 2017. Vol. 7. No. 9. pp. 6347-6351.
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TY - JOUR
DO - 10.1021/acscatal.7b02066
UR - https://doi.org/10.1021/acscatal.7b02066
TI - Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide
T2 - ACS Catalysis
AU - Surya Prakash, G. K.
AU - Kar, Sayan
AU - Goeppert, Alain
AU - Kothandaraman, Jotheeswari
PY - 2017
DA - 2017/08/23
PB - American Chemical Society (ACS)
SP - 6347-6351
IS - 9
VL - 7
SN - 2155-5435
ER -
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BibTex
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@article{2017_Kar,
author = {G. K. Surya Prakash and Sayan Kar and Alain Goeppert and Jotheeswari Kothandaraman},
title = {Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide},
journal = {ACS Catalysis},
year = {2017},
volume = {7},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acscatal.7b02066},
number = {9},
pages = {6347--6351},
doi = {10.1021/acscatal.7b02066}
}
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MLA
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Kar, Sayan, et al. “Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide.” ACS Catalysis, vol. 7, no. 9, Aug. 2017, pp. 6347-6351. https://doi.org/10.1021/acscatal.7b02066.