ACS Catalysis

, том 8 , издание 2 , страницы 802-806

Photoredox C–F Quaternary Annulation Catalyzed by a Strongly Reducing Iridium Species

Тип публикации: Journal Article

Дата публикации: 2017-12-29

American Chemical Society (ACS)

ACS Catalysis

SCImago Q1

Tоп 10% SCImago

WOS Q1

БС1

SJR: 3.541

CiteScore: 20.4

Impact factor: 13.6

ISSN: 21555435

DOI: 10.1021/acscatal.7b03089

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General Chemistry

Catalysis

Краткое описание

We report a fac–Ir(ppy)3*–IrII–IrIII photocatalytic cycle involving t-BuOK as the terminal reductant in a visible-light-induced sp2 C–F quaternary annulation reaction that proceeds in yields up to 98%. Because of the high activity of the IrII(ppy)3 catalyst, even at a loading of 50 ppm, the annulation reaction was able to compete with an uncatalyzed nucleophilic aromatic substitution reaction. The annulation reaction was stereoconvergent, and an annulated product was synthesized with complete retention of enantiomeric excess.

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Dai P. et al. Photoredox C–F Quaternary Annulation Catalyzed by a Strongly Reducing Iridium Species // ACS Catalysis. 2017. Vol. 8. No. 2. pp. 802-806.

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Dai P., Ma J., Huang W., Chen W., Wu N., Wu S., Li Y., Cheng X., Tan R. X. Photoredox C–F Quaternary Annulation Catalyzed by a Strongly Reducing Iridium Species // ACS Catalysis. 2017. Vol. 8. No. 2. pp. 802-806.

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TY - JOUR

DO - 10.1021/acscatal.7b03089

UR - https://doi.org/10.1021/acscatal.7b03089

TI - Photoredox C–F Quaternary Annulation Catalyzed by a Strongly Reducing Iridium Species

T2 - ACS Catalysis

AU - Dai, Peng

AU - Ma, Junyu

AU - Huang, Wenhao

AU - Chen, Wenxin

AU - Wu, Na

AU - Wu, Shengfu

AU - Li, Ying

AU - Cheng, Xu

AU - Tan, Ren Xiang

PY - 2017

DA - 2017/12/29

PB - American Chemical Society (ACS)

SP - 802-806

IS - 2

VL - 8

SN - 2155-5435

ER -

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@article{2017_Dai,

author = {Peng Dai and Junyu Ma and Wenhao Huang and Wenxin Chen and Na Wu and Shengfu Wu and Ying Li and Xu Cheng and Ren Xiang Tan},

title = {Photoredox C–F Quaternary Annulation Catalyzed by a Strongly Reducing Iridium Species},

journal = {ACS Catalysis},

year = {2017},

volume = {8},

publisher = {American Chemical Society (ACS)},

month = {dec},

url = {https://doi.org/10.1021/acscatal.7b03089},

number = {2},

pages = {802--806},

doi = {10.1021/acscatal.7b03089}

}

MLA

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MLA Скопировать

Dai, Peng, et al. “Photoredox C–F Quaternary Annulation Catalyzed by a Strongly Reducing Iridium Species.” ACS Catalysis, vol. 8, no. 2, Dec. 2017, pp. 802-806. https://doi.org/10.1021/acscatal.7b03089.

Издатель

American Chemical Society (ACS)

Журнал

ACS Catalysis

SCImago Q1

Tоп 10% SCImago

WOS Q1

БС1

SJR

3.541

CiteScore

20.4