Acyl Radicals from Acylsilanes: Photoredox-Catalyzed Synthesis of Unsymmetrical Ketones
Publication type: Journal Article
Publication date: 2017-12-07
scimago Q1
wos Q1
SJR: 3.782
CiteScore: 19.5
Impact factor: 13.1
ISSN: 21555435
General Chemistry
Catalysis
Abstract
Acyl radicals were smoothly generated from acylsilanes under photoredox-catalyzed conditions. These radicals were formed upon ultraviolet B (UV-B), solar, or visible light irradiation by using decatungstate and acridinium salts as photocatalysts. Acylation of Michael acceptors and a few styrenes resulted in a smooth preparation of unsymmetrical ketones in yields up to 89%.
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Metrics
122
Total citations:
122
Citations from 2024:
29
(23.77%)
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MLA
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GOST
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Capaldo L. et al. Acyl Radicals from Acylsilanes: Photoredox-Catalyzed Synthesis of Unsymmetrical Ketones // ACS Catalysis. 2017. Vol. 8. No. 1. pp. 304-309.
GOST all authors (up to 50)
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Capaldo L., Riccardi R., Ravelli D., Fagnoni M. Acyl Radicals from Acylsilanes: Photoredox-Catalyzed Synthesis of Unsymmetrical Ketones // ACS Catalysis. 2017. Vol. 8. No. 1. pp. 304-309.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acscatal.7b03719
UR - https://doi.org/10.1021/acscatal.7b03719
TI - Acyl Radicals from Acylsilanes: Photoredox-Catalyzed Synthesis of Unsymmetrical Ketones
T2 - ACS Catalysis
AU - Capaldo, Luca
AU - Riccardi, Riccardo
AU - Ravelli, Davide
AU - Fagnoni, Maurizio
PY - 2017
DA - 2017/12/07
PB - American Chemical Society (ACS)
SP - 304-309
IS - 1
VL - 8
SN - 2155-5435
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Capaldo,
author = {Luca Capaldo and Riccardo Riccardi and Davide Ravelli and Maurizio Fagnoni},
title = {Acyl Radicals from Acylsilanes: Photoredox-Catalyzed Synthesis of Unsymmetrical Ketones},
journal = {ACS Catalysis},
year = {2017},
volume = {8},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/acscatal.7b03719},
number = {1},
pages = {304--309},
doi = {10.1021/acscatal.7b03719}
}
Cite this
MLA
Copy
Capaldo, Luca, et al. “Acyl Radicals from Acylsilanes: Photoredox-Catalyzed Synthesis of Unsymmetrical Ketones.” ACS Catalysis, vol. 8, no. 1, Dec. 2017, pp. 304-309. https://doi.org/10.1021/acscatal.7b03719.