Broad-Scope Rh-Catalyzed Inverse-Sonogashira Reaction Directed by Weakly Coordinating Groups
1
Publication type: Journal Article
Publication date: 2018-02-07
scimago Q1
wos Q1
SJR: 3.782
CiteScore: 19.5
Impact factor: 13.1
ISSN: 21555435
PubMed ID:
29527402
General Chemistry
Catalysis
Abstract
We report the alkynylation of C(sp2)–H bonds with bromoalkynes (inverse-Sonogashira reaction) directed by synthetically useful ester, ketone, and ether groups under rhodium catalysis. Other less common directing groups such as amine, thioether, sulfoxide, sulfone, phenol ester, and carbamate are also suitable directing groups. Mechanistic studies indicate that the reaction proceeds by a turnover-limiting C–H activation step via an electrophilic-type substitution.
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166
Total citations:
166
Citations from 2024:
26
(15.67%)
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GOST
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Tan E. C. et al. Broad-Scope Rh-Catalyzed Inverse-Sonogashira Reaction Directed by Weakly Coordinating Groups // ACS Catalysis. 2018. Vol. 8. No. 3. pp. 2166-2172.
GOST all authors (up to 50)
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Tan E. C., Quinonero O., Elena De Orbe M., Echavarren A. M. Broad-Scope Rh-Catalyzed Inverse-Sonogashira Reaction Directed by Weakly Coordinating Groups // ACS Catalysis. 2018. Vol. 8. No. 3. pp. 2166-2172.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acscatal.7b04395
UR - https://doi.org/10.1021/acscatal.7b04395
TI - Broad-Scope Rh-Catalyzed Inverse-Sonogashira Reaction Directed by Weakly Coordinating Groups
T2 - ACS Catalysis
AU - Tan, Eric C.D.
AU - Quinonero, Ophélie
AU - Elena De Orbe, M
AU - Echavarren, Antonio M.
PY - 2018
DA - 2018/02/07
PB - American Chemical Society (ACS)
SP - 2166-2172
IS - 3
VL - 8
PMID - 29527402
SN - 2155-5435
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Tan,
author = {Eric C.D. Tan and Ophélie Quinonero and M Elena De Orbe and Antonio M. Echavarren},
title = {Broad-Scope Rh-Catalyzed Inverse-Sonogashira Reaction Directed by Weakly Coordinating Groups},
journal = {ACS Catalysis},
year = {2018},
volume = {8},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acscatal.7b04395},
number = {3},
pages = {2166--2172},
doi = {10.1021/acscatal.7b04395}
}
Cite this
MLA
Copy
Tan, Eric C.D., et al. “Broad-Scope Rh-Catalyzed Inverse-Sonogashira Reaction Directed by Weakly Coordinating Groups.” ACS Catalysis, vol. 8, no. 3, Feb. 2018, pp. 2166-2172. https://doi.org/10.1021/acscatal.7b04395.