Rare-Earth-Catalyzed Regioselective Hydrosilylation of Aryl-Substituted Internal Alkenes
Publication type: Journal Article
Publication date: 2018-02-08
scimago Q1
wos Q1
SJR: 3.782
CiteScore: 19.5
Impact factor: 13.1
ISSN: 21555435
General Chemistry
Catalysis
Abstract
Rare-earth-catalyzed regioselective hydrosilylation of internal alkenes with an ene-diamido samarium alkyl as a precatalyst has been described. The samarium alkyl complex LSmCH2SiMe3(THF)2 (2, L = DipNC(Me)C(Me)NDip, where Dip = 2,6-iPr2C6H3) enabled highly regioselective hydrosilylation of aryl-substituted internal alkenes with primary silanes, leading to the selective formation of a series of secondary silanes in high yields.
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58
Total citations:
58
Citations from 2025:
4
(6.9%)
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GOST
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Liu J. et al. Rare-Earth-Catalyzed Regioselective Hydrosilylation of Aryl-Substituted Internal Alkenes // ACS Catalysis. 2018. Vol. 8. No. 3. pp. 2230-2235.
GOST all authors (up to 50)
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Liu J., Chen W., Li J., Cui C. Rare-Earth-Catalyzed Regioselective Hydrosilylation of Aryl-Substituted Internal Alkenes // ACS Catalysis. 2018. Vol. 8. No. 3. pp. 2230-2235.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acscatal.8b00010
UR - https://doi.org/10.1021/acscatal.8b00010
TI - Rare-Earth-Catalyzed Regioselective Hydrosilylation of Aryl-Substituted Internal Alkenes
T2 - ACS Catalysis
AU - Liu, Jinxi
AU - Chen, Wufeng
AU - Li, Jianfeng
AU - Cui, Chunming
PY - 2018
DA - 2018/02/08
PB - American Chemical Society (ACS)
SP - 2230-2235
IS - 3
VL - 8
SN - 2155-5435
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Liu,
author = {Jinxi Liu and Wufeng Chen and Jianfeng Li and Chunming Cui},
title = {Rare-Earth-Catalyzed Regioselective Hydrosilylation of Aryl-Substituted Internal Alkenes},
journal = {ACS Catalysis},
year = {2018},
volume = {8},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acscatal.8b00010},
number = {3},
pages = {2230--2235},
doi = {10.1021/acscatal.8b00010}
}
Cite this
MLA
Copy
Liu, Jinxi, et al. “Rare-Earth-Catalyzed Regioselective Hydrosilylation of Aryl-Substituted Internal Alkenes.” ACS Catalysis, vol. 8, no. 3, Feb. 2018, pp. 2230-2235. https://doi.org/10.1021/acscatal.8b00010.