Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene–Imine [3 + 2] Annulation
Тип публикации: Journal Article
Дата публикации: 2018-05-04
scimago Q1
wos Q1
БС1
SJR: 3.847
CiteScore: 20.8
Impact factor: 13.1
ISSN: 21555435
PubMed ID:
30393576
General Chemistry
Catalysis
Краткое описание
We have prepared a previously unreported family of P-stereogenic [2.2.1] bicyclic chiral phosphines through straightforward syntheses starting from the natural product carvone. This design rationale prompted the development of an unforeseen C-dealkenylation reaction. We have applied these organocatalysts in the asymmetric syntheses of a bevy of pyrrolines, obtained in high yields and enantioselectivities, including a biologically active small molecule, efsevin.
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Smaligo A. J., Sriramurthy V., Kwon O. Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene–Imine [3 + 2] Annulation // ACS Catalysis. 2018. Vol. 8. No. 6. pp. 5188-5192.
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Smaligo A. J., Sriramurthy V., Kwon O. Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene–Imine [3 + 2] Annulation // ACS Catalysis. 2018. Vol. 8. No. 6. pp. 5188-5192.
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TY - JOUR
DO - 10.1021/acscatal.8b01081
UR - https://doi.org/10.1021/acscatal.8b01081
TI - Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene–Imine [3 + 2] Annulation
T2 - ACS Catalysis
AU - Smaligo, Andrew J
AU - Sriramurthy, Vardhineedi
AU - Kwon, Ohyun
PY - 2018
DA - 2018/05/04
PB - American Chemical Society (ACS)
SP - 5188-5192
IS - 6
VL - 8
PMID - 30393576
SN - 2155-5435
ER -
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BibTex (до 50 авторов)
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@article{2018_Smaligo,
author = {Andrew J Smaligo and Vardhineedi Sriramurthy and Ohyun Kwon},
title = {Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene–Imine [3 + 2] Annulation},
journal = {ACS Catalysis},
year = {2018},
volume = {8},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acscatal.8b01081},
number = {6},
pages = {5188--5192},
doi = {10.1021/acscatal.8b01081}
}
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MLA
Скопировать
Smaligo, Andrew J., et al. “Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene–Imine [3 + 2] Annulation.” ACS Catalysis, vol. 8, no. 6, May. 2018, pp. 5188-5192. https://doi.org/10.1021/acscatal.8b01081.