ACS Catalysis, volume 8, issue 8, pages 7201-7207
Manganese-Catalyzed β-Alkylation of Secondary Alcohols with Primary Alcohols under Phosphine-Free Conditions
Publication type: Journal Article
Publication date: 2018-07-05
General Chemistry
Catalysis
Abstract
Manganese(I) complexes bearing a pyridyl-supported pyrazolyl-imidazolyl ligand efficiently catalyzed the direct β-alkylation of secondary alcohols with primary alcohols under phosphine-free conditions. The β-alkylated secondary alcohols were obtained in moderate to good yields with water formed as the byproduct through a borrowing hydrogen pathway. β-Alkylation of cholesterols was also effectively achieved. The present protocol provides a concise atom-economical method for C–C bond formation from primary and secondary alcohols.
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GOST
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Liu T. et al. Manganese-Catalyzed β-Alkylation of Secondary Alcohols with Primary Alcohols under Phosphine-Free Conditions // ACS Catalysis. 2018. Vol. 8. No. 8. pp. 7201-7207.
GOST all authors (up to 50)
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Liu T., Wang L., Wu K., Yu Z. Manganese-Catalyzed β-Alkylation of Secondary Alcohols with Primary Alcohols under Phosphine-Free Conditions // ACS Catalysis. 2018. Vol. 8. No. 8. pp. 7201-7207.
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TY - JOUR
DO - 10.1021/acscatal.8b01960
UR - https://doi.org/10.1021/acscatal.8b01960
TI - Manganese-Catalyzed β-Alkylation of Secondary Alcohols with Primary Alcohols under Phosphine-Free Conditions
T2 - ACS Catalysis
AU - Liu, Tingting
AU - Wang, Liandi
AU - Wu, Kaikai
AU - Yu, Zhengkun
PY - 2018
DA - 2018/07/05
PB - American Chemical Society (ACS)
SP - 7201-7207
IS - 8
VL - 8
SN - 2155-5435
ER -
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BibTex (up to 50 authors)
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@article{2018_Liu,
author = {Tingting Liu and Liandi Wang and Kaikai Wu and Zhengkun Yu},
title = {Manganese-Catalyzed β-Alkylation of Secondary Alcohols with Primary Alcohols under Phosphine-Free Conditions},
journal = {ACS Catalysis},
year = {2018},
volume = {8},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acscatal.8b01960},
number = {8},
pages = {7201--7207},
doi = {10.1021/acscatal.8b01960}
}
Cite this
MLA
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Liu, Tingting, et al. “Manganese-Catalyzed β-Alkylation of Secondary Alcohols with Primary Alcohols under Phosphine-Free Conditions.” ACS Catalysis, vol. 8, no. 8, Jul. 2018, pp. 7201-7207. https://doi.org/10.1021/acscatal.8b01960.