Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis
Тип публикации: Journal Article
Дата публикации: 2018-07-17
scimago Q1
wos Q1
БС1
SJR: 3.782
CiteScore: 19.5
Impact factor: 13.1
ISSN: 21555435
General Chemistry
Catalysis
Краткое описание
A non-noble metal-free protocol has been developed for C–H bond functionalization at room temperature by merging cobalt-mediated catalysis with photocatalysis. The reaction requires only oxygen as sole oxidant and operated at room temperature under redox-neutral conditions. Visible-light activated photoredox catalyst functions as an electron transfer reagent with oxygen as a terminal oxidant in the cobalt-mediated C–H and N–H bond annulation. The developed methodology allows annulations with various coupling partners. The concept demonstrated herein is expected to enhance the scope of cobalt catalysis as applied to sustainable fine chemical synthesis.
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MLA
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ГОСТ
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Kalsi D. et al. Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis // ACS Catalysis. 2018. Vol. 8. No. 9. pp. 8115-8120.
ГОСТ со всеми авторами (до 50)
Скопировать
Kalsi D., Dutta S., Barsu N., Rueping M., Sundararaju B. Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis // ACS Catalysis. 2018. Vol. 8. No. 9. pp. 8115-8120.
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RIS
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TY - JOUR
DO - 10.1021/acscatal.8b02118
UR - https://doi.org/10.1021/acscatal.8b02118
TI - Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis
T2 - ACS Catalysis
AU - Kalsi, Deepti
AU - Dutta, Subhradeep
AU - Barsu, Nagaraju
AU - Rueping, Magnus
AU - Sundararaju, Basker
PY - 2018
DA - 2018/07/17
PB - American Chemical Society (ACS)
SP - 8115-8120
IS - 9
VL - 8
SN - 2155-5435
ER -
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BibTex (до 50 авторов)
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@article{2018_Kalsi,
author = {Deepti Kalsi and Subhradeep Dutta and Nagaraju Barsu and Magnus Rueping and Basker Sundararaju},
title = {Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis},
journal = {ACS Catalysis},
year = {2018},
volume = {8},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acscatal.8b02118},
number = {9},
pages = {8115--8120},
doi = {10.1021/acscatal.8b02118}
}
Цитировать
MLA
Скопировать
Kalsi, Deepti, et al. “Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis.” ACS Catalysis, vol. 8, no. 9, Jul. 2018, pp. 8115-8120. https://doi.org/10.1021/acscatal.8b02118.