Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis
Publication type: Journal Article
Publication date: 2018-07-17
scimago Q1
wos Q1
SJR: 3.782
CiteScore: 19.5
Impact factor: 13.1
ISSN: 21555435
General Chemistry
Catalysis
Abstract
A non-noble metal-free protocol has been developed for C–H bond functionalization at room temperature by merging cobalt-mediated catalysis with photocatalysis. The reaction requires only oxygen as sole oxidant and operated at room temperature under redox-neutral conditions. Visible-light activated photoredox catalyst functions as an electron transfer reagent with oxygen as a terminal oxidant in the cobalt-mediated C–H and N–H bond annulation. The developed methodology allows annulations with various coupling partners. The concept demonstrated herein is expected to enhance the scope of cobalt catalysis as applied to sustainable fine chemical synthesis.
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Metrics
127
Total citations:
127
Citations from 2024:
17
(13%)
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MLA
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GOST
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Kalsi D. et al. Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis // ACS Catalysis. 2018. Vol. 8. No. 9. pp. 8115-8120.
GOST all authors (up to 50)
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Kalsi D., Dutta S., Barsu N., Rueping M., Sundararaju B. Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis // ACS Catalysis. 2018. Vol. 8. No. 9. pp. 8115-8120.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acscatal.8b02118
UR - https://doi.org/10.1021/acscatal.8b02118
TI - Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis
T2 - ACS Catalysis
AU - Kalsi, Deepti
AU - Dutta, Subhradeep
AU - Barsu, Nagaraju
AU - Rueping, Magnus
AU - Sundararaju, Basker
PY - 2018
DA - 2018/07/17
PB - American Chemical Society (ACS)
SP - 8115-8120
IS - 9
VL - 8
SN - 2155-5435
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Kalsi,
author = {Deepti Kalsi and Subhradeep Dutta and Nagaraju Barsu and Magnus Rueping and Basker Sundararaju},
title = {Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis},
journal = {ACS Catalysis},
year = {2018},
volume = {8},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acscatal.8b02118},
number = {9},
pages = {8115--8120},
doi = {10.1021/acscatal.8b02118}
}
Cite this
MLA
Copy
Kalsi, Deepti, et al. “Room-Temperature C–H Bond Functionalization by Merging Cobalt and Photoredox Catalysis.” ACS Catalysis, vol. 8, no. 9, Jul. 2018, pp. 8115-8120. https://doi.org/10.1021/acscatal.8b02118.
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