ACS Catalysis, volume 9, issue 9, pages 8575-8580
Iron-Catalyzed Borrowing Hydrogen β-C(sp3)-Methylation of Alcohols
2
Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, U.K.
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Publication type: Journal Article
Publication date: 2019-08-21
PubMed ID:
32064149
General Chemistry
Catalysis
Abstract
Herein we report the iron-catalyzed β-C(sp3)-methylation of primary alcohols using methanol as a C1 building block. This borrowing hydrogen approach employs a well-defined bench-stable (cyclopentadienone)iron(0) carbonyl complex as precatalyst (5 mol %) and enables a diverse selection of substituted 2-arylethanols to undergo β-C(sp3)-methylation in good isolated yields (24 examples, 65% average yield).
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Polidano K., Williams J. M. J., Morrill L. C. Iron-Catalyzed Borrowing Hydrogen β-C(sp3)-Methylation of Alcohols // ACS Catalysis. 2019. Vol. 9. No. 9. pp. 8575-8580.
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Polidano K., Williams J. M. J., Morrill L. C. Iron-Catalyzed Borrowing Hydrogen β-C(sp3)-Methylation of Alcohols // ACS Catalysis. 2019. Vol. 9. No. 9. pp. 8575-8580.
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TY - JOUR
DO - 10.1021/acscatal.9b02461
UR - https://doi.org/10.1021/acscatal.9b02461
TI - Iron-Catalyzed Borrowing Hydrogen β-C(sp3)-Methylation of Alcohols
T2 - ACS Catalysis
AU - Polidano, Kurt
AU - Williams, Jonathan M J
AU - Morrill, Louis C.
PY - 2019
DA - 2019/08/21
PB - American Chemical Society (ACS)
SP - 8575-8580
IS - 9
VL - 9
PMID - 32064149
SN - 2155-5435
ER -
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@article{2019_Polidano,
author = {Kurt Polidano and Jonathan M J Williams and Louis C. Morrill},
title = {Iron-Catalyzed Borrowing Hydrogen β-C(sp3)-Methylation of Alcohols},
journal = {ACS Catalysis},
year = {2019},
volume = {9},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acscatal.9b02461},
number = {9},
pages = {8575--8580},
doi = {10.1021/acscatal.9b02461}
}
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Polidano, Kurt, et al. “Iron-Catalyzed Borrowing Hydrogen β-C(sp3)-Methylation of Alcohols.” ACS Catalysis, vol. 9, no. 9, Aug. 2019, pp. 8575-8580. https://doi.org/10.1021/acscatal.9b02461.