Open Access
Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions
Xinjiang Cui
1
,
Kathrin Junge
1
,
X. F. Dai
2
,
C. Kreyenschulte
1
,
Marga-Martina Pohl
1
,
Sebastian Wohlrab
1
,
Feng Shi
2
,
A. Brückner
1
,
1
Publication type: Journal Article
Publication date: 2017-05-17
scimago Q1
wos Q1
SJR: 3.286
CiteScore: 19.3
Impact factor: 10.4
ISSN: 23747943, 23747951
PubMed ID:
28691069
General Chemistry
General Chemical Engineering
Abstract
Catalytic hydrosilylation represents a straightforward and atom-efficient methodology for the creation of C–Si bonds. In general, the application of homogeneous platinum complexes prevails in industry and academia. Herein, we describe the first heterogeneous single atom catalysts (SACs), which are conveniently prepared by decorating alumina nanorods with platinum atoms. The resulting stable material efficiently catalyzes hydrosilylation of industrially relevant olefins with high TON (≈105). A variety of substrates is selectively hydrosilylated including compounds with sensitive reducible and other functional groups (N, B, F, Cl). The single atom based catalyst shows significantly higher activity compared to related Pt nanoparticles.
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148
Total citations:
148
Citations from 2024:
29
(19.6%)
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GOST
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Cui X. et al. Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions // ACS Central Science. 2017. Vol. 3. No. 6. pp. 580-585.
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Cui X., Junge K., Dai X. F., Kreyenschulte C., Pohl M., Wohlrab S., Shi F., Brückner A., Beller M. Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions // ACS Central Science. 2017. Vol. 3. No. 6. pp. 580-585.
Cite this
RIS
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TY - JOUR
DO - 10.1021/acscentsci.7b00105
UR - https://doi.org/10.1021/acscentsci.7b00105
TI - Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions
T2 - ACS Central Science
AU - Cui, Xinjiang
AU - Junge, Kathrin
AU - Dai, X. F.
AU - Kreyenschulte, C.
AU - Pohl, Marga-Martina
AU - Wohlrab, Sebastian
AU - Shi, Feng
AU - Brückner, A.
AU - Beller, Matthias
PY - 2017
DA - 2017/05/17
PB - American Chemical Society (ACS)
SP - 580-585
IS - 6
VL - 3
PMID - 28691069
SN - 2374-7943
SN - 2374-7951
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Cui,
author = {Xinjiang Cui and Kathrin Junge and X. F. Dai and C. Kreyenschulte and Marga-Martina Pohl and Sebastian Wohlrab and Feng Shi and A. Brückner and Matthias Beller},
title = {Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions},
journal = {ACS Central Science},
year = {2017},
volume = {3},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/acscentsci.7b00105},
number = {6},
pages = {580--585},
doi = {10.1021/acscentsci.7b00105}
}
Cite this
MLA
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Cui, Xinjiang, et al. “Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions.” ACS Central Science, vol. 3, no. 6, May. 2017, pp. 580-585. https://doi.org/10.1021/acscentsci.7b00105.